Diversity of strontium nitridogermanates(IV) : novel Sr4[GeN4], Sr8Ge2[GeN4], and Sr17Ge2[GeN3]2[GeN4]2

Link, Lukas; Niewa, Rainer

Diversity of strontium nitridogermanates(IV) : novel Sr4[GeN4], Sr8Ge2[GeN4], and Sr17Ge2[GeN3]2[GeN4]2

dc.contributor.author	Link, Lukas
dc.contributor.author	Niewa, Rainer
dc.date.accessioned	2024-07-12T09:28:23Z
dc.date.available	2024-07-12T09:28:23Z
dc.date.issued	2020	de
dc.date.updated	2023-11-14T06:17:27Z
dc.description.abstract	Single crystals of three new strontium nitridogermanates(IV) were grown in sealed niobium ampules from sodium flux. Dark red Sr4[GeN4] crystallizes in space group P21/c with a = 9.7923(2) Å, b = 6.3990(1) Å, c = 11.6924(3) Å and β = 115.966(1)°. Black Sr8Ge2[GeN4] contains Ge4- anions coexisting with [GeIVN4]8- tetrahedra and adopts space group Cc with a = 10.1117(4) Å, b = 17.1073(7) Å, c = 10.0473(4) Å and β = 115.966(1)°. Black Sr17Ge6N14 features the same anions alongside trigonal planar [GeIVN3]5- units. It crystallizes in P1 with a = 7.5392(1) Å, b = 9.7502(2) Å, c = 11.6761(2) Å, α = 103.308(1)°, β = 94.651(1)° and γ = 110.248(1)°.	en
dc.description.sponsorship	Projekt DEAL	de
dc.identifier.issn	1521-3749
dc.identifier.issn	0044-2313
dc.identifier.other	1895516633
dc.identifier.uri	http://nbn-resolving.de/urn:nbn:de:bsz:93-opus-ds-146601	de
dc.identifier.uri	http://elib.uni-stuttgart.de/handle/11682/14660
dc.identifier.uri	http://dx.doi.org/10.18419/opus-14641
dc.language.iso	en	de
dc.relation.uri	doi:10.1002/zaac.202000008	de
dc.rights	info:eu-repo/semantics/openAccess	de
dc.rights.uri	https://creativecommons.org/licenses/by/4.0/	de
dc.subject.ddc	540	de
dc.title	Diversity of strontium nitridogermanates(IV) : novel Sr4[GeN4], Sr8Ge2[GeN4], and Sr17Ge2[GeN3]2[GeN4]2	en
dc.type	article	de
ubs.fakultaet	Chemie	de
ubs.institut	Institut für Anorganische Chemie	de
ubs.publikation.seiten	1105-1109	de
ubs.publikation.source	Zeitschrift für anorganische und allgemeine Chemie 646 (2020), S. 1105-1109	de
ubs.publikation.typ	Zeitschriftenartikel	de

Files

Original bundle

Now showing 1 - 1 of 1

Name:: ZAAC_ZAAC202000008.pdf
Size:: 1.39 MB
Format:: Adobe Portable Document Format

Download

License bundle

Now showing 1 - 1 of 1

Name:: license.txt
Size:: 3.3 KB
Format:: Item-specific license agreed upon to submission
Description:

Download

Collections

03 Fakultät Chemie