Darstellung, physikalische Eigenschaften und Kristallstrukturen von Mono-, Di- und Trichlor-2,4,6-tris(dialkylamino)benzolen (Aminobenzole ; 22)
dc.contributor.author | Effenberger, Franz | de |
dc.contributor.author | Mündl, Gabriele | de |
dc.date.accessioned | 2009-08-28 | de |
dc.date.accessioned | 2016-03-31T07:47:45Z | |
dc.date.available | 2009-08-28 | de |
dc.date.available | 2016-03-31T07:47:45Z | |
dc.date.issued | 1992 | de |
dc.description.abstract | Mono-, di- and trichlorotris(dialkylamino)benzenes 2,3, and 4 are prepared selectively by chlorination of triaminobenzenes 1 with one, two, or three equivalents of N-chlorosuccinimide, resp., in tetrachloromethane. From spectroscopic data it is deduced that the introduction of chloro substituents into symmetrical triaminobenzenes 1 causes a severe steric hindrance for the dialkylamino groups without disturbing the aromatic π system. X-ray structural analyses of the trichlorotriamino compounds 4a and 4c confirm the spectroscopic interpretation. Among the trichloro compounds 4a - d only for 4c the anodic oxidation is reversible. | en |
dc.identifier.other | 312087322 | de |
dc.identifier.uri | http://nbn-resolving.de/urn:nbn:de:bsz:93-opus-44245 | de |
dc.identifier.uri | http://elib.uni-stuttgart.de/handle/11682/1164 | |
dc.identifier.uri | http://dx.doi.org/10.18419/opus-1147 | |
dc.language.iso | de | de |
dc.rights | info:eu-repo/semantics/openAccess | de |
dc.subject.classification | Anilin | de |
dc.subject.ddc | 540 | de |
dc.title | Darstellung, physikalische Eigenschaften und Kristallstrukturen von Mono-, Di- und Trichlor-2,4,6-tris(dialkylamino)benzolen (Aminobenzole ; 22) | de |
dc.title.alternative | Synthesis, physical properties, and crystal structures of mono-, di-, and trichloro-2,4,6-tris(dialky1amino)benzenes (Aminobenzenes ; 22) | en |
dc.type | article | de |
ubs.fakultaet | Fakultät Chemie | de |
ubs.institut | Institut für Organische Chemie | de |
ubs.opusid | 4424 | de |
ubs.publikation.source | Chemische Berichte 125 (1992), S. 247-254. URL http://dx.doi.org./10.1002/cber.19921250139 | de |
ubs.publikation.typ | Zeitschriftenartikel | de |