Darstellung, physikalische Eigenschaften und Kristallstrukturen von Mono-, Di- und Trichlor-2,4,6-tris(dialkylamino)benzolen (Aminobenzole ; 22)

dc.contributor.authorEffenberger, Franzde
dc.contributor.authorMündl, Gabrielede
dc.date.accessioned2009-08-28de
dc.date.accessioned2016-03-31T07:47:45Z
dc.date.available2009-08-28de
dc.date.available2016-03-31T07:47:45Z
dc.date.issued1992de
dc.description.abstractMono-, di- and trichlorotris(dialkylamino)benzenes 2,3, and 4 are prepared selectively by chlorination of triaminobenzenes 1 with one, two, or three equivalents of N-chlorosuccinimide, resp., in tetrachloromethane. From spectroscopic data it is deduced that the introduction of chloro substituents into symmetrical triaminobenzenes 1 causes a severe steric hindrance for the dialkylamino groups without disturbing the aromatic π system. X-ray structural analyses of the trichlorotriamino compounds 4a and 4c confirm the spectroscopic interpretation. Among the trichloro compounds 4a - d only for 4c the anodic oxidation is reversible.en
dc.identifier.other312087322de
dc.identifier.urihttp://nbn-resolving.de/urn:nbn:de:bsz:93-opus-44245de
dc.identifier.urihttp://elib.uni-stuttgart.de/handle/11682/1164
dc.identifier.urihttp://dx.doi.org/10.18419/opus-1147
dc.language.isodede
dc.rightsinfo:eu-repo/semantics/openAccessde
dc.subject.classificationAnilinde
dc.subject.ddc540de
dc.titleDarstellung, physikalische Eigenschaften und Kristallstrukturen von Mono-, Di- und Trichlor-2,4,6-tris(dialkylamino)benzolen (Aminobenzole ; 22)de
dc.title.alternativeSynthesis, physical properties, and crystal structures of mono-, di-, and trichloro-2,4,6-tris(dialky1amino)benzenes (Aminobenzenes ; 22)en
dc.typearticlede
ubs.fakultaetFakultät Chemiede
ubs.institutInstitut für Organische Chemiede
ubs.opusid4424de
ubs.publikation.sourceChemische Berichte 125 (1992), S. 247-254. URL http://dx.doi.org./10.1002/cber.19921250139de
ubs.publikation.typZeitschriftenartikelde

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