1,2- and 1,3-diphosphetanes from alkylidenephosphines
| dc.contributor.author | Becker, Gerd | de |
| dc.contributor.author | Becker, Winfried | de |
| dc.contributor.author | Uhl, Gudrun | de |
| dc.contributor.author | Uhl, Werner | de |
| dc.contributor.author | Wessely, Hans-Jürgen | de |
| dc.date.accessioned | 2010-11-15 | de |
| dc.date.accessioned | 2016-03-31T07:48:08Z | |
| dc.date.available | 2010-11-15 | de |
| dc.date.available | 2016-03-31T07:48:08Z | |
| dc.date.issued | 1983 | de |
| dc.date.updated | 2014-09-11 | de |
| dc.description.abstract | Alkyl- or arylbis(trimethylsilyl)phosphines as well as tris(trimethylsilyl)phosphine and the corresponding arsines react with acyl chlorides to give [1-(trimethylsiloxy)alkylidene]phosphines 1 and -arsines 2; most of their 2,2-dimethylpropylidene derivatives are thermally stable at room temperature. With the same class of phosphines as starting compounds and carbon disulfide [bis(trimethylsilylsulfano)methylidene]phosphines 3 are formed, whereas [(dialkylamino)methylidene]-4 and [diarylmethylidene]phosphines 5 or the corresponding arsines 6 and 7 can be obtained from acyl amides or ketones. | en |
| dc.identifier.other | 340324171 | de |
| dc.identifier.uri | http://nbn-resolving.de/urn:nbn:de:bsz:93-opus-57695 | de |
| dc.identifier.uri | http://elib.uni-stuttgart.de/handle/11682/1293 | |
| dc.identifier.uri | http://dx.doi.org/10.18419/opus-1276 | |
| dc.language.iso | en | de |
| dc.rights | info:eu-repo/semantics/openAccess | de |
| dc.subject.classification | Alkylphosphane | de |
| dc.subject.ddc | 540 | de |
| dc.title | 1,2- and 1,3-diphosphetanes from alkylidenephosphines | en |
| dc.type | article | de |
| ubs.fakultaet | Fakultät Chemie | de |
| ubs.institut | Institut für Anorganische Chemie | de |
| ubs.opusid | 5769 | de |
| ubs.publikation.source | Phosphorus and sulfur and the related elements 18 (1983), S. 7-10. URL http://dx.doi.org./10.1080/03086648308075954 | de |
| ubs.publikation.typ | Zeitschriftenartikel | de |