Universität Stuttgart

Permanent URI for this communityhttps://elib.uni-stuttgart.de/handle/11682/1

Browse

Filters

2023 - 20252

Settings

Institute: search.filters.UBSInstitut.Fakultätsübergreifend / Sonstige EinrichtungAuthor: search.filters.author.Gross, Joachim

Search Results

Now showing 1 - 2 of 2
  • Thumbnail Image
    ItemOpen Access
    Characterisation of the transient mixing behaviour of evaporating near-critical droplets
    (2023) Steinhausen, Christoph; Gerber, Valerie; Stierle, Rolf; Preusche, Andreas; Dreizler, Andreas; Gross, Joachim; Weigand, Bernhard; Lamanna, Grazia
    With technical progress, combustion pressures have been increased over the years, frequently exceeding the critical pressure of the injected fluids. For conditions beyond the critical point of the injected fluids, the fundamental physics of mixing and evaporation processes is not yet fully understood. In particular, quantitative data for validation of numerical simulations and analytical models remain sparse. In previous works, transient speed of sound studies applying laser-induced thermal acoustics (LITA) have been conducted to investigate the mixing behaviour in the wake of an evaporating droplet injected into a supercritical atmosphere. LITA is a seedless, non-intrusive measurement technique capable of direct speed of sound measurements within these mixing processes. The used setup employs a high-repetition-rate excitation laser source and, therefore, allows the acquisition of time-resolved speed of sound data. For the visualisation of the evaporation process, measurements are accompanied by direct, high-speed shadowgraphy. In the present work, the measured speed of sound data are evaluated by applying an advection-controlled mixing assumption to estimate both the local mole fraction and mixing temperature. For this purpose, planar spontaneous Raman scattering results measured under the same operating conditions are evaluated using an advection-controlled mixing assumption with the perturbed-chain statistical associating fluid theory (PC-SAFT) equation of state. Successively, the resulting concentration–temperature field is used for the estimation of local mixture parameters from the detected speed of sound data. Moreover, models using the PC-SAFT equation of state and the NIST database for the computation of the speed of sound are compared. The investigations indicate a classical two-phase evaporation process with evaporative cooling of the droplet. The subsequent mixing of fluid vapour and ambient gas also remains subcritical in the direct vicinity of the droplet.
  • Thumbnail Image
    ItemOpen Access
    Process-based screening of porous materials for vacuum swing adsorption based on 1D classical density functional theory and PC-SAFT
    (2025) Mayer, Fabian; Buhk, Benedikt; Schilling, Johannes; Rehner, Philipp; Gross, Joachim; Bardow, André
    Adsorption-based processes are showing substantial potential for carbon capture. Due to the vast space of potential solid adsorbents and their influence on the process performance, the choice of the material is not trivial but requires systematic approaches. In particular, the material choice should be based on the performance of the resulting process. In this work, we present a method for the process-based screening of porous materials for pressure and vacuum swing adsorption. The method is based on an equilibrium process model that incorporates one-dimensional classical density functional theory (1D-DFT) and the PC-SAFT equation of state. Thereby, the presented method can efficiently screen databases of potential adsorbents and identify the best-performing materials as well as the corresponding optimized process conditions for a specific carbon capture application. We apply our method to a point-source carbon capture application at a cement plant. The results show that the process model is crucial to evaluating the performance of adsorbents instead of relying solely on material heuristics. Furthermore, we enhance our approach through multi-objective optimization and demonstrate for materials with high performance that our method is able to capture the trade-offs between two process objectives, such as specific work and purity. The presented method thus provides an efficient screening tool for adsorbents to maximize process performance.