Universität Stuttgart

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Institute: search.filters.UBSInstitut.Fakultätsübergreifend / Sonstige EinrichtungAuthor: search.filters.author.Thiele, Simon

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Now showing 1 - 5 of 5
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    Tailored nanocomposites for 3D printed micro-optics
    (2020) Weber, Ksenia; Werdehausen, Daniel; König, Peter; Thiele, Simon; Schmid, Michael; Decker, Manuel; Oliveira, Peter William de; Herkommer, Alois; Giessen, Harald
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    Synthesis and characterization of novel perfluoro aromatic side chain sulfonated PSU ionomers
    (2024) Martschin, Philipp; Atanasov, Vladimir; Thiele, Simon; Kerres, Jochen
    Polyethersulfone (PSU) as a commercially available polymer offers many different opportunities for functionalization for diverse fields of application, for example, electrophilic substitutions like sulfonation and bromination or nucleophilic reactions such as lithiation. This study presents three different polysulfone derivatives, first functionalized by a lithiation reaction, followed by a reaction with carbonyl compounds containing pentafluorophenyl groups. In the last step, the pentafluorophenyl moieties of the modified PSU were sulfonated by thiolation and subsequent oxidation to sulfonic acid groups. Those novel PSU derivatives were characterized by NMR, DSC, TGA, GPC, and titration. Based on these ionomers, we show the fabrication of pure and acid-base blend membranes with promising proton conductivities. These novel sulfonic acid groups containing materials are potentially promising candidates for membranes or ionomers in electrochemical applications such as proton exchange membrane fuel cells (PEMFCs), proton exchange membrane water electrolysis (PEMWEs), or redox flow batteries (RFBs).
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    3D direct laser writing of highly absorptive photoresist for miniature optical apertures
    (2022) Schmid, Michael D.; Toulouse, Andrea; Thiele, Simon; Mangold, Simon; Herkommer, Alois; Giessen, Harald
    The importance of 3D direct laser writing as an enabling technology increased rapidly in recent years. Complex micro-optics and optical devices with various functionalities are now feasible. Different possibilities to increase the optical performance are demonstrated, for example, multi-lens objectives, a combination of different photoresists, or diffractive optical elements. It is still challenging to create fitting apertures for these micro optics. In this work, a novel and simple way to create 3D-printed opaque structures with a highly absorptive photoresist is introduced, which can be used to fabricate microscopic apertures increasing the contrast of 3D-printed micro optics and enabling new optical designs. Both hybrid printing by combining clear and opaque resists, as well as printing transparent optical elements and their surrounding opaque apertures solely from a single black resist by using different printing thicknesses are demonstrated.
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    Ultrathin monolithic 3D printed optical coherence tomography endoscopy for preclinical and clinical use
    (2020) Li, Jiawen; Thiele, Simon; Quirk, Bryden C.; Kirk, Rodney W.; Verjans, Johan W.; Akers, Emma; Bursill, Christina A.; Nicholls, Stephen J.; Herkommer, Alois; Giessen, Harald; McLaughlin, Robert A.
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    3D printed micro-optics for quantum technology: Optimised coupling of single quantum dot emission into a single-mode fibre
    (2021) Sartison, Marc; Weber, Ksenia; Thiele, Simon; Bremer, Lucas; Fischbach, Sarah; Herzog, Thomas; Kolatschek, Sascha; Jetter, Michael; Reitzenstein, Stephan; Herkommer, Alois; Michler, Peter; Portalupi, Simone Luca; Giessen, Harald