Universität Stuttgart
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Item Open Access Counterion effects on the mesomorphic and electrochemical properties of guanidinium salts(2024) Ebert, Max; Lange, Alyna; Müller, Michael; Wuckert, Eugen; Gießelmann, Frank; Klamroth, Tillmann; Zens, Anna; Taubert, Andreas; Laschat, SabineIonic liquid crystals (ILCs) combine the ion mobility of ionic liquids with the order and self-assembly of thermotropic mesophases. To understand the role of the anion in ILCs, wedge-shaped arylguanidinium salts with tetradecyloxy side chains were chosen as benchmark systems and their liquid crystalline self-assembly in the bulk phase as well as their electrochemical behavior in solution were studied depending on the anion. Differential scanning calorimetry (DSC), polarizing optical microscopy (POM) and X-ray diffraction (WAXS, SAXS) experiments revealed that for spherical anions, the phase width of the hexagonal columnar mesophase increased with the anion size, while for non-spherical anions, the trends were less clear cut. Depending on the anion, the ILCs showed different stability towards electrochemical oxidation and reduction with the most stable being the PF6 based compound. Cyclic voltammetry (CV) and density functional theory (DFT) calculations suggest a possible contribution of the guanidinium cation to the oxidation processes.Item Open Access We are all pattern makers! : how a flat ontology connects organizational routines and grand challenges(2024) Sele, Kathrin; Mahringer, Christian A; Danner-Schröder, Anja; Grisold, Thomas; Renzl, BirgitAdopting a flat ontology, we discuss how phenomena of societal concern are connected to organizational routines. We conceptualize grand challenges as large patterns of actions to overcome the micro-macro divide prevalent in existing research. We introduce spatial, temporal, and agentic relations as three interrelated aspects of scale that are of particular interest and demonstrate how social phenomena may be approached through these relations. Focusing on the situated enactment of routines allows us to identify weakening and strengthening between actors and their actions as important processes that reflect the continuous patterning of grand challenges. We contribute to the literature by highlighting the consequentiality of mundane actions and by questioning the dominant approach to change in research on grand challenges. Our insights offer several practical implications for intervening on grand challenges.Item Open Access Lateral torsional buckling of glulam beam-columns : axial compression and bending verification(2024) Töpler, Janusch; Kuhlmann, Ulrike; Schänzlin, JörgItem Open Access Computational optimisation of urban design models : a systematic literature review(2024) Tay, JingZhi; Ortner, Frederick Peter; Wortmann, Thomas; Aydin, Elif EsraThe densification of urban spaces globally has contributed to a need for design tools supporting the planning of more sustainable, efficient, and liveable cities. Urban Design Optimisation (UDO) responds to this challenge by providing a means to explore many design solutions for a district, evaluate multiple objectives, and make informed selections from many Pareto-efficient solutions. UDO distinguishes itself from other forms of design optimisation by addressing the challenges of incorporating a wide range of planning goals, managing the complex interactions among various urban datasets, and considering the social-technical aspects of urban planning involving multiple stakeholders. Previous reviews focusing on specific topics within UDO do not sufficiently address these challenges. This PRISMA systematic literature review provides an overview of research on topics related to UDO from 2012 to 2022, with articles analysed across seven descriptive categories. This paper presents a discussion on the state-of-the-art and identified gaps present in each of the seven categories. Finally, this paper argues that additional research to improve the socio-technical understanding and usability of UDO would require: (i) methods of optimisation across multiple models, (ii) interfaces that address a multiplicity of stakeholders, (iii) exploration of frameworks for scenario building and backcasting, and (iv) advancing AI applications for UDO, including generalizable surrogates and user preference learning.Item Open Access Driving profiles of light commercial vehicles of craftsmen and the potential of battery electric vehicles when charging on company premises(2024) Heilmann, Oliver; Bocho, Britta; Frieß, Alexander; Cortès, Sven; Schrade, Ulrich; Casal Kulzer, André; Schlick, MichaelThis paper examines the extent to which it is possible to replace conventional light commercial vehicles in the heating, ventilation and air conditioning and plumbing trade with battery electric vehicles with an unchanged usage profile. GPS trackers are used to record the position data of 22 craft vehicles with combustion engines from eleven companies over the duration of one working week. Within this paper, various assumptions (battery capacity and average consumption) are made for battery electric vehicles and the charging power on the company premises. The potential of battery electric vehicles is evaluated based on the assumption that they are charged only on company premises. Using the collected data and the assumptions made, theoretical state of charge curves are calculated for the vehicles. The driving profiles of the individual vehicles differ greatly, and the suitability of battery electric vehicles should be considered individually. Battery capacity, vehicle energy consumption and charging power at the company have a substantial influence on the suitability of battery electric vehicles. Furthermore, there are differences between vehicles that can charge on the company premises at night and those that cannot or can only do so on some days.Item Open Access Editorial - professional and vocational identity development(2024) Wuttke, Eveline; Heinrichs, Karin; Hillen, Stefanie A.; Kögler, KristinaItem Open Access VisRecall++: analysing and predicting visualisation recallability from gaze behaviour(2024) Wang, Yao; Jiang, Yue; Hu, Zhiming; Ruhdorfer, Constantin; Bâce, Mihai; Bulling, AndreasQuestion answering has recently been proposed as a promising means to assess the recallability of information visualisations. However, prior works are yet to study the link between visually encoding a visualisation in memory and recall performance. To fill this gap, we propose VisRecall++ - a novel 40-participant recallability dataset that contains gaze data on 200 visualisations and five question types, such as identifying the title, and finding extreme values.We measured recallability by asking participants questions after they observed the visualisation for 10 seconds.Our analyses reveal several insights, such as saccade amplitude, number of fixations, and fixation duration significantly differ between high and low recallability groups.Finally, we propose GazeRecallNet - a novel computational method to predict recallability from gaze behaviour that outperforms several baselines on this task.Taken together, our results shed light on assessing recallability from gaze behaviour and inform future work on recallability-based visualisation optimisation.Item Open Access Advances in additive friction extrusion deposition (AFED) : process and tool design(2024) Hossfeld, Max; Wright, ArnoldAdditive friction extrusion deposition (AFED) is a recently developed additive manufacturing technique that promises high deposition rates at low forces. Due to the novelty of the process, the underlying phenomena and their interactions are not fully understood, and in particular, the processing strategy and tool design are still in their infancy. This work contributes to the state-of-the-art of AFED through a comprehensive analysis of its working principles and an experimental program, including a representative sample component. The working principle and process mechanics of AFED are broken down into their individual components. The forces and their origins and effects on the process are described, and measures of process efficiency and theoretical minimum energy consumption are derived. Three geometrical features of the extrusion die were identified as most relevant to the active material flow, process forces, and deposition quality: the topography of the inner and outer circular surfaces and the geometry of its extrusion channels. Based on this, the experimental program investigated seven different tool designs in terms of efficiency, force reduction, and throughput. The experiments using AA 6061-T6 as feedstock show that AFED is capable of both high material throughput (close to 550 mm3/s) and reduced substrate forces, for example, the forces for a run at 100 mm3/s remained continuously below 500 N and for a run at 400 mm3/s below 3500 N. The material flow and microstructure of AFED were assessed from macro-sections. Significant differences were found between the advancing and retracting sides for both process effects and material flow. Banded structures in the microstructure show strong similarities to other solid-state processes. The manufacturing of the sample components demonstrates that AFED is already capable of producing industrial-grade components. In mechanical tests, interlayer bonding defects resulted in more brittle failure behavior in the build direction of the structure, whereas in the horizontal direction, mechanical properties corresponding to a T4 temper were achieved.Item Open Access Generation of mechanical characteristics in workpiece subsurface layers through milling(2024) Storchak, Michael; Hlembotska, Larysa; Melnyk, OleksandrThe generation of mechanical characteristics in workpiece subsurface layers as a result of the cutting process has a predominant influence on the performance properties of machined parts. The effect of the end milling process on the mechanical characteristics of the machined subsurface layers was evaluated using nondestructive methods: instrumented nanoindentation and sclerometry (scratching). In this paper, the influence of one of the common processes of materials processing by cutting-the process of end tool milling-on the generation of mechanical characteristics of workpiece machined subsurface layers is studied. The effect of the end milling process on the character of mechanical property formation was evaluated through the coincidence of the cutting process energy characteristics with the mechanical characteristics of the machined subsurface layers. The total cutting power and cutting work in the tertiary cutting zone area were used as energy characteristics of the end milling process. The modes of the end milling process are considered as the main parameters affecting these energy characteristics. The mechanical characteristics of the workpiece machined subsurface layers were the microhardness of the subsurface layers and the total work of indenter penetration, determined by instrumental nanoindentation, and the maximum depth of indenter penetration, determined by sclerometry. Titanium alloy Ti10V2Fe3Al (Ti-1023) was used as the machining material. Based on the evaluation of the coincidence of the cutting process energy characteristics with the specified mechanical characteristics of the machined subsurface layers, the milling mode effect of the studied titanium alloy, in particular the cutter feed and cutting speed, on the generated mechanical characteristics was established.Item Open Access Surface charge density and induced currents by self-charging sliding drops(2024) Bista, Pravash; Ratschow, Aaron D.; Stetten, Amy Z.; Butt, Hans-Jürgen; Weber, Stefan A. L.Spontaneous charge separation in drops sliding over a hydrophobized insulator surface is a well-known phenomenon and lots of efforts have been made to utilize this effect for energy harvesting. For maximizing the efficiency of such devices, a comprehensive understanding of the dewetted surface charge would be required to quantitatively predict the electric current signals, in particular for drop sequences. Here, we use a method based on mirror charge detection to locally measure the surface charge density after drops move over a hydrophobic surface. For this purpose, we position a metal electrode beneath the hydrophobic substrate to measure the capacitive current induced by the moving drop. Furthermore, we investigate drop-induced charging on different dielectric surfaces together with the surface neutralization processes. The surface neutralizes over a characteristic time, which is influenced by the substrate and the surrounding environment. We present an analytical model that describes the slide electrification using measurable parameters such as the surface charge density and its neutralization time. Understanding the model parameters and refining them will enable a targeted optimization of the efficiency in solid–liquid charge separation.