Rapid aging as a key to understand deactivation of Ni/Al2O3 catalysts applied for the CO2 methanation

Abstract

We developed a rapid aging method for Ni/Al2O3 methanation catalysts mimicking the real aging in the actual application. The method is based on hydrothermal deactivation of the catalyst at 600 or 700 °C, which leads to a catalyst with nearly constant conversion after a much shorter time period compared to normal aging. The hydrothermally aged catalysts are characterized by N2 adsorption, X-ray powder diffraction, temperature-programmed reduction and H2 chemisorption. The catalytic performance of the aged catalysts is comparable to the one of a catalyst deactivated in a long-term measurement with up to 720 h on stream. The time needed for reaching a stable conversion can be diminished by rapid aging by a factor of 10. The investigations also showed that the long-term deactivation is caused by Ni particle sintering and that the support pores limit the Ni particle size.