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http://dx.doi.org/10.18419/opus-13637
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DC Element | Wert | Sprache |
---|---|---|
dc.contributor.author | Stein, Felix | - |
dc.contributor.author | Suhr, Simon | - |
dc.contributor.author | Singha Hazari, Arijit | - |
dc.contributor.author | Walter, Robert | - |
dc.contributor.author | Nößler, Maite | - |
dc.contributor.author | Sarkar, Biprajit | - |
dc.date.accessioned | 2023-10-18T08:52:51Z | - |
dc.date.available | 2023-10-18T08:52:51Z | - |
dc.date.issued | 2023 | de |
dc.identifier.issn | 0947-6539 | - |
dc.identifier.issn | 1521-3765 | - |
dc.identifier.other | 1869936329 | - |
dc.identifier.uri | http://nbn-resolving.de/urn:nbn:de:bsz:93-opus-ds-136564 | de |
dc.identifier.uri | http://elib.uni-stuttgart.de/handle/11682/13656 | - |
dc.identifier.uri | http://dx.doi.org/10.18419/opus-13637 | - |
dc.description.abstract | Mesoionic carbenes (MIC) are a popular class of compound that are heavily investigated at the moment. The access to cationic MICs, and the ability of MICs to stabilize radicals are two highly attractive fields that have hardly been explored until now. Here the synthesis and characterisation of three different cationic azide-substituted 1,2,3-triazolium salts, used as building blocks for studying their reactivity towards triphenylphosphine are reported, where the reactivity is dependent on the nature of the starting triazolium salt. Furthermore, the cationic triazolium salts were used to develop a series of unsymmetrical MIC-triazene-NHC/MIC’ compounds, which can be readily converted to the radical form either by electrochemical or chemical methods. These radicals, which display NIR electrochromism, were investigated using a battery of techniques such as electrochemistry, UV/Vis/NIR and EPR spectroelectrochemistry, and theoretical calculations. Interestingly, the MIC plays an important role in the stabilization of the triazenyl radical, particularly in a competitive role vis-à-vis their NHC counterparts. These results shed new light on the ability of MICs to stabilize radicals, and possibly also on their π-accepting ability. | en |
dc.description.sponsorship | H2020 Marie Skłodowska-Curie Actions | de |
dc.description.sponsorship | Deutsche Forschungsgemeinschaft | de |
dc.description.sponsorship | Projekt DEAL | de |
dc.language.iso | en | de |
dc.relation | info:eu-repo/grantAgreement/EC/H2020/894082 | de |
dc.relation.uri | doi:10.1002/chem.202300771 | de |
dc.rights | info:eu-repo/semantics/openAccess | de |
dc.rights.uri | https://creativecommons.org/licenses/by/4.0/ | de |
dc.subject.ddc | 540 | de |
dc.title | Azide‐substituted 1,2,3‐triazolium salts as useful synthetic synthons : access to triazenyl radicals and Staudinger type reactivity | en |
dc.type | article | de |
dc.date.updated | 2023-07-11T23:38:13Z | - |
ubs.fakultaet | Chemie | de |
ubs.fakultaet | Fakultätsübergreifend / Sonstige Einrichtung | de |
ubs.institut | Institut für Anorganische Chemie | de |
ubs.institut | Fakultätsübergreifend / Sonstige Einrichtung | de |
ubs.publikation.seiten | 10 | de |
ubs.publikation.source | Chemistry - a European journal 29 (2023), No. e202300771 | de |
ubs.publikation.typ | Zeitschriftenartikel | de |
Enthalten in den Sammlungen: | 03 Fakultät Chemie |
Dateien zu dieser Ressource:
Datei | Beschreibung | Größe | Format | |
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CHEM_CHEM202300771.pdf | 1,62 MB | Adobe PDF | Öffnen/Anzeigen |
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