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http://dx.doi.org/10.18419/opus-13648
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DC Element | Wert | Sprache |
---|---|---|
dc.contributor.author | Stein, Felix | - |
dc.contributor.author | Nößler, Maite | - |
dc.contributor.author | Singha Hazari, Arijit | - |
dc.contributor.author | Böser, Lisa | - |
dc.contributor.author | Walter, Robert | - |
dc.contributor.author | Liu, Hang | - |
dc.contributor.author | Klemm, Elias | - |
dc.contributor.author | Sarkar, Biprajit | - |
dc.date.accessioned | 2023-10-19T08:43:17Z | - |
dc.date.available | 2023-10-19T08:43:17Z | - |
dc.date.issued | 2023 | de |
dc.identifier.issn | 0947-6539 | - |
dc.identifier.issn | 1521-3765 | - |
dc.identifier.other | 186990608X | - |
dc.identifier.uri | http://nbn-resolving.de/urn:nbn:de:bsz:93-opus-ds-136672 | de |
dc.identifier.uri | http://elib.uni-stuttgart.de/handle/11682/13667 | - |
dc.identifier.uri | http://dx.doi.org/10.18419/opus-13648 | - |
dc.description.abstract | In recent years terpyridines (tpy) and mesoionic carbenes (MIC) have been widely used in metal complexes. With the right combination with a metal center, both of these ligands are individually known to generate excellent catalysts for CO2 reduction. In this study, we combine the potentials of PFC (PFC=polyfluorocarbon) substituted tpy and MIC ligands within the same platform to obtain a new class of complexes, which we investigated with respect to their structural, electrochemical and UV/Vis/NIR spectroelectrochemical properties. We further show that the resulting metal complexes are potent electrocatalysts for CO2 reduction in which CO is exclusively formed with a faradaic efficiency of 92 %. A preliminary mechanistic study, including the isolation and characterization of a key intermediate is also reported. | en |
dc.description.sponsorship | Deutsche Forschungsgemeinschaft | de |
dc.description.sponsorship | HORIZON EUROPE 2020 | de |
dc.description.sponsorship | Projekt DEAL | de |
dc.language.iso | en | de |
dc.relation | info:eu-repo/grantAgreement/EC/H2020/894082 | de |
dc.relation.uri | doi:10.1002/chem.202300405 | de |
dc.rights | info:eu-repo/semantics/openAccess | de |
dc.rights.uri | https://creativecommons.org/licenses/by/4.0/ | de |
dc.subject.ddc | 540 | de |
dc.title | Ruthenium complexes of polyfluorocarbon substituted terpyridine and mesoionic carbene ligands : an interplay in CO2 reduction | en |
dc.type | article | de |
dc.date.updated | 2023-07-12T00:27:50Z | - |
ubs.fakultaet | Chemie | de |
ubs.fakultaet | Fakultätsübergreifend / Sonstige Einrichtung | de |
ubs.institut | Institut für Anorganische Chemie | de |
ubs.institut | Institut für Technische Chemie | de |
ubs.institut | Fakultätsübergreifend / Sonstige Einrichtung | de |
ubs.publikation.seiten | 11 | de |
ubs.publikation.source | Chemistry - a European journal 29 (2023), No. e22300405 | de |
ubs.publikation.typ | Zeitschriftenartikel | de |
Enthalten in den Sammlungen: | 03 Fakultät Chemie |
Dateien zu dieser Ressource:
Datei | Beschreibung | Größe | Format | |
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CHEM_CHEM202300405.pdf | 2,08 MB | Adobe PDF | Öffnen/Anzeigen |
Diese Ressource wurde unter folgender Copyright-Bestimmung veröffentlicht: Lizenz von Creative Commons