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http://dx.doi.org/10.18419/opus-14513
Autor(en): | Altmann, Hagen J. Steinmann, Mark Elser, Iris Benedikter, Mathis J. Naumann, Stefan Buchmeiser, Michael R. |
Titel: | Dual catalysis with an N‐heterocyclic carbene and a Lewis acid : thermally latent precatalyst for the polymerization of ε‐caprolactam |
Erscheinungsdatum: | 2020 |
Dokumentart: | Zeitschriftenartikel |
Seiten: | 3219-3226 |
Erschienen in: | Journal of polymer science 58 (2020), S. 3219-3226 |
URI: | http://nbn-resolving.de/urn:nbn:de:bsz:93-opus-ds-145324 http://elib.uni-stuttgart.de/handle/11682/14532 http://dx.doi.org/10.18419/opus-14513 |
ISSN: | 2642-4169 2642-4150 |
Zusammenfassung: | So far, the earlier reported strong correlation between basicity of an N‐heterocyclic carbene (NHC) and its reactivity in poly(ε‐caprolactam) (PA6) synthesis resulted in a substantial limitation of applicable carbenes. Here, to overcome this issue, 1,3‐dimethylimidazolium‐2‐carboxylate, an easily accessible, air and moisture‐stable NHC, was applied as thermally latent initiator. In order to compensate for its low basicity, reactivity was enhanced by the addition of both a Lewis acid and an activator to ease the initial polymerization step. The resulting mixtures of ε‐caprolactam, the CO2‐protected NHC, a Lewis acid and N‐acylazepan‐2‐one constitute homogeneous, thermally fully latent “single‐component” blends for the anionic polymerization‐based synthesis of PA6. They can be stored both in the liquid and solid state for days and months, respectively, without any loss in activity. The role of the Lewis acid as well as technical implications of the prolonged pot‐times are discussed. |
Enthalten in den Sammlungen: | 03 Fakultät Chemie |
Dateien zu dieser Ressource:
Datei | Beschreibung | Größe | Format | |
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POLA_POLA29850.pdf | 1,24 MB | Adobe PDF | Öffnen/Anzeigen |
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