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Autor(en): Altmann, Hagen J.
Steinmann, Mark
Elser, Iris
Benedikter, Mathis J.
Naumann, Stefan
Buchmeiser, Michael R.
Titel: Dual catalysis with an N‐heterocyclic carbene and a Lewis acid : thermally latent precatalyst for the polymerization of ε‐caprolactam
Erscheinungsdatum: 2020
Dokumentart: Zeitschriftenartikel
Seiten: 3219-3226
Erschienen in: Journal of polymer science 58 (2020), S. 3219-3226
URI: http://nbn-resolving.de/urn:nbn:de:bsz:93-opus-ds-145324
http://elib.uni-stuttgart.de/handle/11682/14532
http://dx.doi.org/10.18419/opus-14513
ISSN: 2642-4169
2642-4150
Zusammenfassung: So far, the earlier reported strong correlation between basicity of an N‐heterocyclic carbene (NHC) and its reactivity in poly(ε‐caprolactam) (PA6) synthesis resulted in a substantial limitation of applicable carbenes. Here, to overcome this issue, 1,3‐dimethylimidazolium‐2‐carboxylate, an easily accessible, air and moisture‐stable NHC, was applied as thermally latent initiator. In order to compensate for its low basicity, reactivity was enhanced by the addition of both a Lewis acid and an activator to ease the initial polymerization step. The resulting mixtures of ε‐caprolactam, the CO2‐protected NHC, a Lewis acid and N‐acylazepan‐2‐one constitute homogeneous, thermally fully latent “single‐component” blends for the anionic polymerization‐based synthesis of PA6. They can be stored both in the liquid and solid state for days and months, respectively, without any loss in activity. The role of the Lewis acid as well as technical implications of the prolonged pot‐times are discussed.
Enthalten in den Sammlungen:03 Fakultät Chemie

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