Please use this identifier to cite or link to this item:
http://dx.doi.org/10.18419/opus-14844
Authors: | Buyens, Dominique M. S. Pilcher, Lynne A. Roduner, Emil |
Title: | Towards a molecular understanding of cation‐anion interactions and self‐aggregation of adeninate salts in DMSO by NMR and UV spectroscopy and crystallography |
Issue Date: | 2021 |
metadata.ubs.publikation.typ: | Zeitschriftenartikel |
metadata.ubs.publikation.seiten: | 2025-2033 |
metadata.ubs.publikation.source: | ChemPhysChem 22 (2021), S. 2025-2033 |
URI: | http://nbn-resolving.de/urn:nbn:de:bsz:93-opus-ds-148639 http://elib.uni-stuttgart.de/handle/11682/14863 http://dx.doi.org/10.18419/opus-14844 |
ISSN: | 1439-7641 1439-4235 |
Abstract: | Rare anionic forms of nucleic acids play a significant biological role and lead to spontaneous mutations and replication and translational errors. There is a lack of information surrounding the stability and reactivity of these forms. Ion pairs of mono‐sodium and ‐potassium salts of adenine exist in DMSO solution with possible cation coordination sites at the N1, N7 and N9 atoms of the purine ring. At increasing concentrations π‐π stacked dimers are the predominant species of aggregates followed by higher order aggregation governed by coordination to metal cations in which the type of counter ion present has a central role in the aggregate formation. |
Appears in Collections: | 03 Fakultät Chemie |
Files in This Item:
File | Description | Size | Format | |
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CPHC_CPHC202100098.pdf | 2,07 MB | Adobe PDF | View/Open |
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