Please use this identifier to cite or link to this item:
http://dx.doi.org/10.18419/opus-14849
| Authors: | Filippou, Vasileios Blickle, Svenja Bubrin, Martina Kaim, Wolfgang |
| Title: | Intramolecular charge transfer in ruthenium complexes [Ru(acac)2(ciq)] with ambidentate camphoriminoquinone (ciq) ligands |
| Issue Date: | 2021 |
| metadata.ubs.publikation.typ: | Zeitschriftenartikel |
| metadata.ubs.publikation.seiten: | 525-533 |
| metadata.ubs.publikation.source: | Zeitschrift für anorganische und allgemeine Chemie 647 (2021), S. 525-533 |
| URI: | http://nbn-resolving.de/urn:nbn:de:bsz:93-opus-ds-148685 http://elib.uni-stuttgart.de/handle/11682/14868 http://dx.doi.org/10.18419/opus-14849 |
| ISSN: | 1521-3749 0044-2313 |
| Abstract: | Reaction of [Ru(acac)2(MeCN)2], acac−=acetylacetonate, with N‐phenylcamphoriminoquinone (pciq) or the new N‐(2‐thiomethylphenyl)‐camphoriminoquinone (tciq) produces complexes [Ru(acac)2(pciq)] and [Ru(acac)2(tciq)] with N,O or N,S coordination and E or Z configuration at the C=N bond, respectively. Oxidation state assignments in comparison with classical iminoquinone ligands are based on structural data in connection with DFT calculations. Reversible oxidation yields complex ions [RuIII(acac)2(pciq)]+ and [RuIII(acac)2(tciq)]+ as characterized by EPR, IR and UV‐vis‐NIR spectroelectrochemistry. |
| Appears in Collections: | 03 Fakultät Chemie |
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| File | Description | Size | Format | |
|---|---|---|---|---|
| ZAAC_ZAAC202000464.pdf | 1,68 MB | Adobe PDF | View/Open |
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