Please use this identifier to cite or link to this item: http://dx.doi.org/10.18419/opus-2001
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dc.contributor.authorEngesser, Karl-Heinrichde
dc.contributor.authorFietz, Walter H.de
dc.contributor.authorFischer, Peterde
dc.contributor.authorSchulte, P.de
dc.contributor.authorKnackmuss, Hans-Joachimde
dc.date.accessioned2012-08-15de
dc.date.accessioned2016-03-31T07:53:16Z-
dc.date.available2012-08-15de
dc.date.available2016-03-31T07:53:16Z-
dc.date.issued1990de
dc.identifier.other371087139de
dc.identifier.urihttp://nbn-resolving.de/urn:nbn:de:bsz:93-opus-76309de
dc.identifier.urihttp://elib.uni-stuttgart.de/handle/11682/2018-
dc.identifier.urihttp://dx.doi.org/10.18419/opus-2001-
dc.description.abstractA bacterial strain, Pseudomonas sp. POB 310, was enriched with 4-carboxy biphenyl ether as sole source of carbon and energy. Resting cells of POB 310 co-oxidize a substrate analogue, 4-carboxybenzophenone, yielding 1,2-dihydro-1,2-dihydroxy-4-carboxy-benzophenone. The ether bond of 3- and 4-carboxy biphenyl ether is cleaved analogously by initial 1,2-dioxygenation, yielding a hemiacetal which is hydrolysed to proto-catechuate and phenol. These intermediates are degraded via an ortho and meta pathway, respectively. Alternative 2,3- and 3,4-dioxygenation can be ruled out as triggering steps in carboxy biphenyl ether degradation.en
dc.language.isoende
dc.rightsinfo:eu-repo/semantics/openAccessde
dc.subject.classificationPseudomonas , Biaryle , Phenole , Mikrobieller Abbaude
dc.subject.ddc570de
dc.titleDioxygenolytic cleavage of aryl ether bonds: 1,2-Dihydro-1,2-dihydroxy-4-carboxybenzophenone as evidence for initial 1,2-dioxygenation in 3- and 4-carboxy biphenyl ether degradationen
dc.typearticlede
ubs.fakultaetFakultät Energie-, Verfahrens- und Biotechnikde
ubs.fakultaetFakultät Chemiede
ubs.fakultaetFakultätsübergreifend / Sonstige Einrichtungde
ubs.institutInstitut für Mikrobiologiede
ubs.institutInstitut für Biochemiede
ubs.institutSonstige Einrichtungde
ubs.opusid7630de
ubs.publikation.sourceFEMS microbiology letters 69 (1990), S. 317-321. URL http://dx.doi.org./10.1111/j.1574-6968.1990.tb04251.xde
ubs.publikation.typZeitschriftenartikelde
Appears in Collections:04 Fakultät Energie-, Verfahrens- und Biotechnik

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