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Authors: Mollère, Phillip D.
Bock, Hans
Becker, Gerd
Fritz, Gerhard
Title: Photoelectron spectra and molecular properties. 15, The effects of α- and β-silyl substituents on π-systems
Issue Date: 1972 Zeitschriftenartikel Journal of organometallic chemistry 46 (1972), S. 89-96. URL
Abstract: The photoelectron spectra of substituted ethylenes, H 2 C=CHX (X = H, CH 3, SiH 3, CH 2CH 3, CH 2SiH 3) are discussed in the light of results of CNDO-type molecular orbital calculations. The characteristic shifts of the first bands are explained in terms of a qualitative model for the substituent effects of α- and β-silyl groups upon π-systems.
Appears in Collections:15 Fakultätsübergreifend / Sonstige Einrichtung

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