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Authors: Ziegler, Manfred L.
Balles, Rainer
Nuber, Bernd
Becker, Gerd
Schmidt, Helmut
Kanellakopulos, Basil
Powietzka, Bernhard
Title: (2,2,8,8-tetramethyl-5-oxa-4,6-diphospha-3,6-nonadiene)tetrakis[dicarbonyl(methylcyclopentadienyl)manganese], the first complexed bis(phosphavinyl) ether
Issue Date: 1987 Zeitschriftenartikel Angewandte Chemie, International edition 26 (1987), S. 900-901. URL
Abstract: The title compound 1 is the complex of a novel ligand. It is formed from [(CH3C5H4)Mn(CO)2·thf] and (CH3)3C-C=P, presumably with uptake of H2O. The bis(phosphavinyl) ether in 1 functions as an 8-electron donor toward the four (CH3C5H4)Mn(CO)2 units (abbreviated here as Mn).
Appears in Collections:15 Fakultätsübergreifend / Sonstige Einrichtung

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