Bitte benutzen Sie diese Kennung, um auf die Ressource zu verweisen:
http://dx.doi.org/10.18419/opus-8019
Langanzeige der Metadaten
DC Element | Wert | Sprache |
---|---|---|
dc.contributor.author | Engesser, Karl-Heinrich | de |
dc.contributor.author | Cain, Ronald B. | de |
dc.contributor.author | Knackmuss, Hans-Joachim | de |
dc.date.accessioned | 2012-08-22 | de |
dc.date.accessioned | 2016-03-31T11:44:56Z | - |
dc.date.available | 2012-08-22 | de |
dc.date.available | 2016-03-31T11:44:56Z | - |
dc.date.issued | 1988 | de |
dc.identifier.other | 371407125 | de |
dc.identifier.uri | http://nbn-resolving.de/urn:nbn:de:bsz:93-opus-76524 | de |
dc.identifier.uri | http://elib.uni-stuttgart.de/handle/11682/8036 | - |
dc.identifier.uri | http://dx.doi.org/10.18419/opus-8019 | - |
dc.description.abstract | The TOL plasmid-encoded enzymes of the methyl-benzoate pathway in Pseudomonas putida mt-2 cometabolized 3-trifluoromethyl (TFM)-benzoate. Two products, 3-TFM-1,2-dihydroxy-2-hydrobenzoate (3-TFM-DHB) and 2-hydroxy-6-oxo-7,7,7-trifluoro-hepta-2,4-dienoate (7-TFHOD) were identified chemically and by spectroscopic properties. TFM-substituted analogues of the metabolites of the methylbenzoate pathway were generally converted at drastically reduced rates. The catechol-2,3-dioxygenase from Pseudomonas putida showed moderate turnover rates with 3-TFM-catechol. The catechol-1,2-dioxygenase of Rhodococcus rubropertinctus N657 was totally inhibited by 3-TFM-catechol and did not cleave this substrate. Hammett-type analysis showed the catechol-1,2-dioxygenase reaction to be strongly dependent on the electronic nature of the substituents. Electronegative substituents strongly inhibited catechol cleavage. The catechol-2,3-dioxygenase reaction, however, was only moderately sensitive to electronegative substituents. | en |
dc.language.iso | en | de |
dc.rights | info:eu-repo/semantics/openAccess | de |
dc.subject.classification | Pseudomonas , Stoffwechsel , Benzoate | de |
dc.subject.ddc | 570 | de |
dc.title | Bacterial metabolism of side chain fluorinated aromatics: cometabolism of 3-trifluoromethyl(TFM)-benzoate by Pseudomonas putida (arvilla) mt-2 and Rhodococcus rubropertinctus N657 | en |
dc.type | article | de |
ubs.fakultaet | Fakultätsübergreifend / Sonstige Einrichtung | de |
ubs.fakultaet | Fakultät Energie-, Verfahrens- und Biotechnik | de |
ubs.institut | Sonstige Einrichtung | de |
ubs.institut | Institut für Mikrobiologie | de |
ubs.opusid | 7652 | de |
ubs.publikation.source | Archives of microbiology 149 (1988), S. 188-197. URL http://dx.doi.org./10.1007/BF00422004 | de |
ubs.publikation.typ | Zeitschriftenartikel | de |
Enthalten in den Sammlungen: | 15 Fakultätsübergreifend / Sonstige Einrichtung |
Dateien zu dieser Ressource:
Datei | Beschreibung | Größe | Format | |
---|---|---|---|---|
eng29.pdf | 3,04 MB | Adobe PDF | Öffnen/Anzeigen |
Alle Ressourcen in diesem Repositorium sind urheberrechtlich geschützt.