TCNQ salts of planar metal complex cations: novel molecular conductors and semiconductors

Endres, Helmut; Bongart, August; Nöthe, Dietrich; Hennig, Ingolf; Schweitzer, Dieter; Helberg, Hans W.; Schäfer, Herbert

TCNQ salts of planar metal complex cations: novel molecular conductors and semiconductors

dc.contributor.author	Endres, Helmut	de
dc.contributor.author	Bongart, August	de
dc.contributor.author	Nöthe, Dietrich	de
dc.contributor.author	Hennig, Ingolf	de
dc.contributor.author	Schweitzer, Dieter	de
dc.contributor.author	Helberg, Hans W.	de
dc.contributor.author	Schäfer, Herbert	de
dc.date.accessioned	2011-07-20	de
dc.date.accessioned	2016-03-31T11:43:37Z
dc.date.available	2011-07-20	de
dc.date.available	2016-03-31T11:43:37Z
dc.date.issued	1985	de
dc.description.abstract	The facile variation of positive charge of oxamide oxime metal complexes, caused by acid-base equilibrium, allows the growth of single crystals of their TCNQ salts. 1:1 salts consist of reqular segregated stacks of the components, with metallic room temperature behaviour of the Ni compound, the Pt compound being a semiconductor. Room temperature conductivities are of the order of 10 Siemens per cm. A 2:3 Pt complex TCNQ salt contains segregated acceptor stacks with half a negative charge per molecule. These stacks run perpendicular to mixed stacks -D-D-A-D-D-A-, with integral charges on donors D and acceptors A.	en
dc.identifier.other	35137289X	de
dc.identifier.uri	http://nbn-resolving.de/urn:nbn:de:bsz:93-opus-64314	de
dc.identifier.uri	http://elib.uni-stuttgart.de/handle/11682/7600
dc.identifier.uri	http://dx.doi.org/10.18419/opus-7583
dc.language.iso	en	de
dc.rights	info:eu-repo/semantics/openAccess	de
dc.subject.classification	Metall , Charge-transfer-Komplexe , Leitfähigkeit	de
dc.subject.ddc	530	de
dc.title	TCNQ salts of planar metal complex cations: novel molecular conductors and semiconductors	en
dc.type	article	de
ubs.fakultaet	Fakultätsübergreifend / Sonstige Einrichtung	de
ubs.institut	Sonstige Einrichtung	de
ubs.opusid	6431	de
ubs.publikation.source	Molecular crystals and liquid crystals 120 (1985), S. 365-368	de
ubs.publikation.typ	Zeitschriftenartikel	de

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