Photoelectron spectra and molecular properties. 21, Dimethyl sulfide, methyl silyl sulfide, and disilyl sulfide

dc.contributor.authorMollère, Phillip D.de
dc.contributor.authorBock, Hansde
dc.contributor.authorBecker, Gerdde
dc.contributor.authorFritz, Gerhardde
dc.date.accessioned2010-10-19de
dc.date.accessioned2016-03-31T11:42:55Z
dc.date.available2010-10-19de
dc.date.available2016-03-31T11:42:55Z
dc.date.issued1973de
dc.description.abstractThe photoelectron spectra of methyl and silyl sulfides are assigned on the basis of modified CNDO-SCF-MO calculations. The orbital sequence (2b1, 4a1, 3b2) is found to be independent of conformation. The static geometry of the sulfides is in keeping with a smaller charge shift to sulfur accompanying the carbon-silicon exchange. Comparison of the results wit those of the analogous ethers lends support to the previous assignment of the latter.en
dc.identifier.other348344457de
dc.identifier.urihttp://nbn-resolving.de/urn:nbn:de:bsz:93-opus-57217de
dc.identifier.urihttp://elib.uni-stuttgart.de/handle/11682/7402
dc.identifier.urihttp://dx.doi.org/10.18419/opus-7385
dc.language.isoende
dc.rightsinfo:eu-repo/semantics/openAccessde
dc.subject.classificationPhotoelektronenspektroskopie , Sulfidede
dc.subject.ddc540de
dc.titlePhotoelectron spectra and molecular properties. 21, Dimethyl sulfide, methyl silyl sulfide, and disilyl sulfideen
dc.typearticlede
ubs.fakultaetFakultätsübergreifend / Sonstige Einrichtungde
ubs.institutSonstige Einrichtungde
ubs.opusid5721de
ubs.publikation.sourceJournal of organometallic chemistry 61 (1973), S. 127-132. URL http://dx.doi.org./10.1016/S0022-328X(00)86541-9de
ubs.publikation.typZeitschriftenartikelde

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