Pentamethylcyclopentadienyl[bis(trimethylsilyl)methylen]phosphan - ein Phosphaalken mit einer reaktiven PC-Einfachbindung
| dc.contributor.author | Gudat, Dietrich | de |
| dc.contributor.author | Niecke, Edgar | de |
| dc.contributor.author | Krebs, Bernt | de |
| dc.contributor.author | Dartmann, Mechtild | de |
| dc.date.accessioned | 2012-06-04 | de |
| dc.date.accessioned | 2016-03-31T11:44:49Z | |
| dc.date.available | 2012-06-04 | de |
| dc.date.available | 2016-03-31T11:44:49Z | |
| dc.date.issued | 1985 | de |
| dc.date.updated | 2012-09-03 | de |
| dc.description.abstract | Synthesis, spectroscopic data and X-ray structure determination of a novel phosphaalkene, Me5C5-P=C(SiMe3)2 1, are reported. It is shown by dynamic 1H-NMR spectroscopy that 1 exhibits thermal E/Z-isomerization of the double bond at ambient temperature. Reactions of 1 involve electrophilic attack of the π-system with hard (H+) and soft (Ag+) Lewis-acids, and an unusual cleavage of a PC-single bond on reaction with metal complexes (MeCN)3M(CO)3, (M = Mo, W). | en |
| dc.identifier.other | 37060783X | de |
| dc.identifier.uri | http://nbn-resolving.de/urn:nbn:de:bsz:93-opus-74598 | de |
| dc.identifier.uri | http://elib.uni-stuttgart.de/handle/11682/7996 | |
| dc.identifier.uri | http://dx.doi.org/10.18419/opus-7979 | |
| dc.language.iso | de | de |
| dc.rights | info:eu-repo/semantics/openAccess | de |
| dc.subject.classification | Methylenphosphane , Phosphoalkene | de |
| dc.subject.ddc | 540 | de |
| dc.subject.other | Einfachbindung | de |
| dc.title | Pentamethylcyclopentadienyl[bis(trimethylsilyl)methylen]phosphan - ein Phosphaalken mit einer reaktiven PC-Einfachbindung | de |
| dc.type | article | de |
| ubs.fakultaet | Fakultätsübergreifend / Sonstige Einrichtung | de |
| ubs.institut | Sonstige Einrichtung | de |
| ubs.opusid | 7459 | de |
| ubs.publikation.source | Chimia 39 (1985), S. 277-279 | de |
| ubs.publikation.typ | Zeitschriftenartikel | de |