Reactions of iminophosphanes with chlorotris(triphenylphosphine)rhodium(I): generation and NMR identification of the first iminophosphanerhodium(I) and iminophosphanerhodium(III) complexes

Romanenko, Vadim D.; Ruban, Alexander V.; Roshenko, Alexander B.; Povolotskii, Mark I.; Sarina, Tatjana V.; Gudat, Dietrich; Niecke, Edgar

Reactions of iminophosphanes with chlorotris(triphenylphosphine)rhodium(I): generation and NMR identification of the first iminophosphanerhodium(I) and iminophosphanerhodium(III) complexes

dc.contributor.author	Romanenko, Vadim D.	de
dc.contributor.author	Ruban, Alexander V.	de
dc.contributor.author	Roshenko, Alexander B.	de
dc.contributor.author	Povolotskii, Mark I.	de
dc.contributor.author	Sarina, Tatjana V.	de
dc.contributor.author	Gudat, Dietrich	de
dc.contributor.author	Niecke, Edgar	de
dc.date.accessioned	2012-05-24	de
dc.date.accessioned	2016-03-31T11:44:45Z
dc.date.available	2012-05-24	de
dc.date.available	2016-03-31T11:44:45Z
dc.date.issued	1993	de
dc.description.abstract	Iminophosphanes [RO-P=NAr] (R = Me, 2-MeC6H4; Ar = 2,4,6-Bu'3C6H2) 1a,b react with RhClL3 (L = Ph3P) via ligand exchange to give KP-iminophosphane complexes of rhodium(i) [RhCl(MeOP=NAr)2L] 2 and [PhCl(2-MeC6H4OP=NAr)L2] 3. Under analogous conditions, P-halogenoiminophosphanes [X-P=NAr] (X = Cl, Br, I) 3a–c undergo a facile oxidative addition of the P-X bond, forming five-coordinate iminophosphanerhodium(III) complexes of composition [L2Cl(X)Rh(σ-P=BAr)] 5.	en
dc.identifier.other	370348370	de
dc.identifier.uri	http://nbn-resolving.de/urn:nbn:de:bsz:93-opus-74321	de
dc.identifier.uri	http://elib.uni-stuttgart.de/handle/11682/7975
dc.identifier.uri	http://dx.doi.org/10.18419/opus-7958
dc.language.iso	en	de
dc.rights	info:eu-repo/semantics/openAccess	de
dc.subject.classification	Iminophosphane , NMR-Spektroskopie	de
dc.subject.ddc	540	de
dc.title	Reactions of iminophosphanes with chlorotris(triphenylphosphine)rhodium(I): generation and NMR identification of the first iminophosphanerhodium(I) and iminophosphanerhodium(III) complexes	en
dc.type	article	de
ubs.fakultaet	Fakultätsübergreifend / Sonstige Einrichtung	de
ubs.institut	Sonstige Einrichtung	de
ubs.opusid	7432	de
ubs.publikation.source	Mendeleev communications 3 (1993), S. 7-8. URL http://dx.doi.org/10.1070/MC1993v003n01ABEH000194	de
ubs.publikation.typ	Zeitschriftenartikel	de

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