Application of intramolecular Heck reactions to the preparation of steroid and terpene intermediates having cis A-B ring fusions - model studies for the total synthesis of complex cardenolides

Laschat, Sabine; Narjes, Frank; Overmann, Larry E.

Application of intramolecular Heck reactions to the preparation of steroid and terpene intermediates having cis A-B ring fusions - model studies for the total synthesis of complex cardenolides

dc.contributor.author	Laschat, Sabine	de
dc.contributor.author	Narjes, Frank	de
dc.contributor.author	Overmann, Larry E.	de
dc.date.accessioned	2009-07-21	de
dc.date.accessioned	2016-03-31T11:41:36Z
dc.date.available	2009-07-21	de
dc.date.available	2016-03-31T11:41:36Z
dc.date.issued	1994	de
dc.date.updated	2013-06-14	de
dc.description.abstract	The cis-fused tricyclic dienone 13 is the major product formed from intramolecular Heck cyclization of the dienyl triflate 12 (Scheme I). Similarly, the cis-hexahydrophenanthridine 22 is formed in good yield from Heck cyclization of the aryl triflate 21. This latter conversion demonstrates that allylic ether substitution is compatible with intramolecular Heck chemistry and suggests applications of this chemistry in the synthesis of highly oxidized cardenolides.	en
dc.identifier.other	314601481	de
dc.identifier.uri	http://nbn-resolving.de/urn:nbn:de:bsz:93-opus-41469	de
dc.identifier.uri	http://elib.uni-stuttgart.de/handle/11682/6997
dc.identifier.uri	http://dx.doi.org/10.18419/opus-6980
dc.language.iso	en	de
dc.rights	info:eu-repo/semantics/openAccess	de
dc.subject.classification	Terpene , Cardenolide , Steroide	de
dc.subject.ddc	540	de
dc.title	Application of intramolecular Heck reactions to the preparation of steroid and terpene intermediates having cis A-B ring fusions - model studies for the total synthesis of complex cardenolides	en
dc.type	article	de
ubs.fakultaet	Fakultätsübergreifend / Sonstige Einrichtung	de
ubs.institut	Sonstige Einrichtung	de
ubs.opusid	4146	de
ubs.publikation.source	Tetrahedron 50 (1994), S. 347-358. URL http://dx.doi.org./10.1016/S0040-4020(01)80759-6	de
ubs.publikation.typ	Zeitschriftenartikel	de

Files

Original bundle

Now showing 1 - 1 of 1

Name:: las10.pdf
Size:: 1.02 MB
Format:: Adobe Portable Document Format

Download

License bundle

Now showing 1 - 1 of 1

Name:: license.txt
Size:: 1021 B
Format:: Plain Text
Description:

Download

Collections

15 Fakultätsübergreifend / Sonstige Einrichtung