Synthesis of a phosphavinyl complex via shift of a pentamethylcyclopentadienyl from phosphorus to iron

Gudat, Dietrich; Niecke, Edgar; Arif, Atta M.; Cowley, Alan H.; Quashie, Sapé

Synthesis of a phosphavinyl complex via shift of a pentamethylcyclopentadienyl from phosphorus to iron

dc.contributor.author	Gudat, Dietrich	de
dc.contributor.author	Niecke, Edgar	de
dc.contributor.author	Arif, Atta M.	de
dc.contributor.author	Cowley, Alan H.	de
dc.contributor.author	Quashie, Sapé	de
dc.date.accessioned	2012-06-18	de
dc.date.accessioned	2016-03-31T11:44:49Z
dc.date.available	2012-06-18	de
dc.date.available	2016-03-31T11:44:49Z
dc.date.issued	1986	de
dc.description.abstract	The reaction of the phosphaalkene (μ1-Me5C5)P=C(SiMe3)2 with Fe2(CO)9 affords the μ1 (P-bonded) complex (μ1-Me5C5)[(CO)4Fe]P=C(SiMe3)2 (4). Photolysis of 4 produces the phosphavinyl complex [Fe-{μ1-P=C(SiMe3)2}(η5-Me5C5)(CO)2] (5). Compound 5 can also be prepared via the metathetical reaction of (Me3Si)2C=PCl with K[Fe(η5-Me5C5)(CO)2]. The structure of 5 has been determined by X-ray crystallography.	en
dc.identifier.other	370632370	de
dc.identifier.uri	http://nbn-resolving.de/urn:nbn:de:bsz:93-opus-74689	de
dc.identifier.uri	http://elib.uni-stuttgart.de/handle/11682/7999
dc.identifier.uri	http://dx.doi.org/10.18419/opus-7982
dc.language.iso	en	de
dc.rights	info:eu-repo/semantics/openAccess	de
dc.subject.classification	Phosphoalkene , Metallkomplexe	de
dc.subject.ddc	540	de
dc.title	Synthesis of a phosphavinyl complex via shift of a pentamethylcyclopentadienyl from phosphorus to iron	en
dc.type	article	de
ubs.fakultaet	Fakultätsübergreifend / Sonstige Einrichtung	de
ubs.institut	Sonstige Einrichtung	de
ubs.opusid	7468	de
ubs.publikation.source	Organometallics 5 (1986), S. 593-595. URL http://dx.doi.org./10.1021/om00134a036	de
ubs.publikation.typ	Zeitschriftenartikel	de

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