Superconductivity in polycrystalline pressed pellets of k-(BEDT-TTF)2I3

dc.contributor.authorBalthes, Eduardde
dc.contributor.authorBreining, Angelade
dc.contributor.authorKahlich, Siegfriedde
dc.contributor.authorMoldenhauer, Jörgde
dc.contributor.authorSchweitzer, Dieterde
dc.contributor.authorBele, Petrade
dc.contributor.authorBrunner, Hermannde
dc.contributor.authorHeinen, Ilsabede
dc.contributor.authorNuber, Bernhardde
dc.contributor.authorKeller, Heimo J.de
dc.date.accessioned2011-08-16de
dc.date.accessioned2016-03-31T08:36:24Z
dc.date.available2011-08-16de
dc.date.available2016-03-31T08:36:24Z
dc.date.issued1993de
dc.date.updated2011-08-16de
dc.description.abstractInvestigations of the transport properties of single crystals and polycrystalline pressed samples of K-( BEDT-TTF)2I3 are presented. In contrast to polycrystalline pressed samples of K-(BEDT-TTF)2Cu(NCS)2 and K-(BEDT-TTF)2Cu [N(CN)2]Br those of K-(BEDT-TTF)2I3 show bulk superconductivity indicating that the loss of superconductivity in the first two types of samples is not due to the special structure of the K-phase, but probably due to a disproportionation of Cu1+ under the anisotropic pressure during the preparation of the samples. Annealing the single crystals as well as the polycrystalline pressed samples of K-(BEDT-TTF)2I3 at 75°C for a few days results in a structural transfomation with an increase in the transition temperature for superconductivity (about 8 K for the crystals). IR-spectra indicate a transfomatlon into a structure which is identical with αt-(BED-TTF)2I3 which seems to be the thermodynamically most stable phase of the several (BEDT-TTF)2I3 phases.en
dc.identifier.other35417603Xde
dc.identifier.urihttp://nbn-resolving.de/urn:nbn:de:bsz:93-opus-65736de
dc.identifier.urihttp://elib.uni-stuttgart.de/handle/11682/5064
dc.identifier.urihttp://dx.doi.org/10.18419/opus-5047
dc.language.isoende
dc.rightsinfo:eu-repo/semantics/openAccessde
dc.subject.classificationTetrathiafulvalen , Organischer Supraleiterde
dc.subject.ddc530de
dc.titleSuperconductivity in polycrystalline pressed pellets of k-(BEDT-TTF)2I3en
dc.typearticlede
ubs.fakultaetFakultät Mathematik und Physikde
ubs.fakultaetFakultätsübergreifend / Sonstige Einrichtungde
ubs.institut3. Physikalisches Institutde
ubs.institutSonstige Einrichtungde
ubs.opusid6573de
ubs.publikation.sourceSynthetic metals 56 (1993), S. 2859-2864de
ubs.publikation.typZeitschriftenartikelde

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