04 Fakultät Energie-, Verfahrens- und Biotechnik
Permanent URI for this collectionhttps://elib.uni-stuttgart.de/handle/11682/5
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Item Open Access To prevent or promote grid expansion? : analyzing the future role of power transmission in the European energy system(2021) Cao, Karl-Kiên; Pregger, Thomas; Haas, Jannik; Lens, HendrikFuture energy supply systems must become more flexible than they are today to accommodate the significant contributions expected from intermittent renewable power sources. Although numerous studies on planning flexibility options have emerged over the last few years, the uncertainties related to model-based studies have left the literature lacking a proper understanding of the investment strategy needed to ensure robust power grid expansion. To address this issue, we focus herein on two important aspects of these uncertainties: the first is the relevance of various social preferences for the use of certain technologies, and the second is how the available approaches affect the flexibility options for power transmission in energy system models. To address these uncertainties, we analyze a host of scenarios. We use an energy system optimization model to plan the transition of Europe’s energy system. In addition to interacting with the heating and transport sectors, the model integrates power flows in three different ways: as a transport model, as a direct current power flow model, and as a linearized alternating current power flow model based on profiles of power transfer distribution factors. The results show that deploying transmission systems contribute significantly to system adequacy. If investments in new power transmission infrastructure are restricted - for example, because of social opposition - additional power generation and storage technologies are an alternative option to reach the necessary level of adequacy at 2% greater system costs. The share of power transmission in total system costs remains widely stable around 1.5%, even if cost assumptions or the approaches for modeling power flows are varied. Thus, the results indicate the importance of promoting investments in infrastructure projects that support pan-European power transmission. However, a wide range of possibilities exists to put this strategy into practice.Item Open Access Bridging granularity gaps to decarbonize large‐scale energy systems : the case of power system planning(2021) Cao, Karl‐Kiên; Haas, Jannik; Sperber, Evelyn; Sasanpour, Shima; Sarfarazi, Seyedfarzad; Pregger, Thomas; Alaya, Oussama; Lens, Hendrik; Drauz, Simon R.; Kneiske, Tanja M.The comprehensive evaluation of strategies for decarbonizing large‐scale energy systems requires insights from many different perspectives. In energy systems analysis, optimization models are widely used for this purpose. However, they are limited in incorporating all crucial aspects of such a complex system to be sustainably transformed. Hence, they differ in terms of their spatial, temporal, technological, and economic perspective and either have a narrow focus with high resolution or a broad scope with little detail. Against this background, we introduce the so‐called granularity gaps and discuss two possibilities to address them: increasing the resolutions of the established optimization models, and the different kinds of model coupling. After laying out open challenges, we propose a novel framework to design power systems in particular. Our exemplary concept exploits the capabilities of power system optimization, transmission network simulation, distribution grid planning, and agent‐based simulation. This integrated framework can serve to study the energy transition with greater comprehensibility and may be a blueprint for similar multimodel analyses.Item Open Access Regionale Energie- und Umweltanalyse für die Region Hochrhein-Bodensee : Kurzfassung(Waldshut-Tiengen : Regionalverband Hochrhein-Bodensee, 1989) Müller, Thomas; Boysen, Barbara; Fahl, Ulrich; Friedrich, Rainer; Kaltschmitt, Martin; Kuntze, Richard; Voß, Alfred; Giesecke, Jürgen; Jorde, Klaus; Voigt, C.In dem Gutachten wird auf der Grundlage der Erfassung des Energieverbrauchs und der Emissionen in der Region Hochrhein-Bodensee im Jahre 1986 ein Referenzszenario aufgebaut, in dem Annahmen über die Entwicklung des Energieverbrauchs und der Emissionen bis zum Jahre 2000 berechnet werden. Das Gutachten untersucht die Ausschöpfung weiterer Möglichkeiten der Energieeinsparung und die Nutzung weiterer Möglichkeiten zur Emissionsminderung in der Region. Eine umfangreiche und eingehende Untersuchung ist den Möglichkeiten der Verwendung regenerativer Energiequellen in der Region gewidmet. Insbesondere wird auch ein verstärkter Ausbau der Kraft-Wärme-Kopplung untersucht. Die wichtigsten Ergebnisse der Analyse liegen auch auf Gemeindebasis vor, so daß den Gemeinden in der Region wertvolle Handlungshinweise für ihre zukünftige Energiepolitik angeboten werden können. Der Regionalverband wird die Regionale Energie- und Umweltanalyse- in vollem Umfang veröffentlichen. Er schickt in dem vorliegenden Heft eine Zusammenfassung voraus, um erste Ergebnisse möglichst rasch zu veröffentlichen.Item Open Access Scalable fabrication of multi-layered Cu-based electrodes via solvent-free method for the selective electrochemical conversion of CO2 to C2+ products(2024) Chen, Qinhao; Kube, Alexander; Rana, Bhawna; Biswas, Indro; Morawietz, Tobias; Kopljar, Dennis; Friedrich, Kaspar AndreasIn the research field of CO2 electroreduction, gas diffusion electrodes (GDEs) are predominantly manufactured through solvent-based processes. Meanwhile, the solvent-free method has gained heightened attention due to its potential to reduce operational and production expenses, while considering ecological aspects such as solvent evaporation, circulation, and waste treatment. Drawing from its successful applications in other fields, we have specifically developed a solvent-free manufacturing method to produce multi-layered Cu-based GDEs for CO2 electroreduction. The procedure is compatible with industrial production lines, specifically through a roll-to-roll process. By evaluating the interplay between production parameters and electrochemical performance of GDEs via various characterization methods, key factors, i.e., hydrophobicity, gas permeability, thickness, and pore size, were adjusted and applied to achieve a highly selective GDE towards C2+ products (alcohols and ethylene) at industrial relevant currents up to 300 mA cm-2 (ethylene ∼40%, ethanol ∼10%, n-propanol ∼15%).Item Open Access Hydrogen oxidation artifact during platinum oxide reduction in cyclic voltammetry analysis of low-loaded PEMFC electrodes(2020) Prass, Sebastian; St-Pierre, J.; Klingele, Matthias; Friedrich, K. Andreas; Zamel, NadaAn artifact appearing during the cathodic transient of cyclic voltammograms (CVs) of low-loaded platinum on carbon (Pt/C) electrodes in proton exchange membrane fuel cells (PEMFCs) was examined. The artifact appears as an oxidation peak overlapping the reduction peak associated to the reduction of platinum oxide (PtOx). By varying the nitrogen (N2) purge in the working electrode (WE), gas pressures in working and counter electrode, upper potential limits and scan rates of the CVs, the artifact magnitude and potential window could be manipulated. From the results, the artifact is assigned to crossover hydrogen (H2X) accumulating in the WE, once the electrode is passivated towards hydrogen oxidation reaction (HOR) due to PtOx coverage. During the cathodic CV transient, PtOx is reduced and HOR spontaneously occurs with the accumulated H2X, resulting in the overlap of the PtOx reduction with the oxidation peak. This feature is expected to occur predominantly in CV analysis of low-loaded electrodes made of catalyst material, whose oxide is inactive towards HOR. Further, it is only measurable while the N2 purge of the WE is switched off during the CV measurement. For higher loaded electrodes, the artifact is not observed as the electrocatalysts are not fully inactivated towards HOR due to incomplete oxide coverage, and/or the currents associated with the oxide reduction are much larger than the spontaneous HOR of accumulated H2X. However, owing to the forecasted reduction in noble metal loadings of catalyst in PEMFCs, this artifact is expected to be observed more often in the future.Item Open Access In situ laboratory for plastic degradation in the Red Sea(2022) Brümmer, Franz; Schnepf, Uwe; Resch, Julia; Jemmali, Raouf; Abdi, Rahma; Kamel, Hesham Mostafa; Bonten, Christian; Müller, Ralph-WalterDegradation and fragmentation of plastics in the environment are still poorly understood. This is partly caused by the lack of long-term studies and methods that determine weathering duration. We here present a novel study object that preserves information on plastic age: microplastic (MP) resin pellets from the wreck of the SS Hamada, a ship that foundered twenty-nine years ago at the coast of Wadi el Gemal national park, Egypt. Its sinking date enabled us to precisely determine how long MP rested in the wreck and a nearby beach, on which part of the load was washed off. Pellets from both sampling sites were analyzed by microscopy, X-ray tomography, spectroscopy, calorimetry, gel permeation chromatography, and rheology. Most pellets were made of low-density polyethylene, but a minor proportion also consisted of high-density polyethylene. MP from inside the wreck showed no signs of degradation compared to pristine reference samples. Contrary, beached plastics exhibited changes on all structural levels, which sometimes caused fragmentation. These findings provide further evidence that plastic degradation under saltwater conditions is comparatively slow, whereas UV radiation and high temperatures on beaches are major drivers of that process. Future long-term studies should focus on underlying mechanisms and timescales of plastic degradation.Item Open Access Investigation of the degradation phenomena of a proton exchange membrane electrolyzer stack by successive replacement of aged components in single cells(2025) Kimmel, Benjamin; Morawietz, Tobias; Biswas, Indro; Sata, Noriko; Gazdzicki, Pawel; Gago, Aldo Saul; Friedrich, Kaspar AndreasDue to their compactness and high flexibility to operate under dynamic conditions, proton exchange membrane water electrolyzers (PEMWEs) are ideal systems for the production of green hydrogen from renewable energy sources. For the widespread implementation of PEMWEs, an understanding of their degradation mechanism is crucial. In this work, we analyze a commercial PEMWE stack via a novel approach of breaking down from the stack to the single-cell level. Therefore, the disassembled stack components are cut to fit into single cells. Then, the aged components are successively replaced with pristine or regenerated components (cleaned and polished), and electrochemical characterizations are conducted to investigate the contributions of the individual components on performance losses. In addition, several underlying degradation phenomena are identified using different physical ex-situ analysis methods. The catalyst-coated membrane (CCM) contributes the most to performance degradation because of contamination and ionomer rearrangement. Additionally, traces of calcium, likely due to insufficient water purification used during operation or for cleaning the cell components, were found. Significant oxidation was observed on the anodic components, while the electronic conductivity on the cathode side remained unchanged. The combination of electrochemical characterization with stepwise regeneration processes and physical ex-situ analysis allows to draw conclusions about the impact of different components on degradation and to analyze the underlying aging mechanisms occurring in each component.