04 Fakultät Energie-, Verfahrens- und Biotechnik
Permanent URI for this collectionhttps://elib.uni-stuttgart.de/handle/11682/5
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Item Open Access Lab-scale investigation of palm shell char as tar reforming catalyst(2020) Chen, Yen-Hau; Schmid, Max; Chang, Chia-Chi; Chang, Ching-Yuan; Scheffknecht, GünterThis research investigated the application of palm shell char as a catalyst for the catalytic steam reforming of tar after the sorption enhanced gasification (SEG) process. The catalytic activities of palm shell char and metal-supported palm shell char were tested in a simulated SEG derived syngas with tar model compounds (i.e., toluene and naphthalene) at a concentration of 10 g m-3 NTP. The results indicated that palm shell char had an experimentally excellent catalytic activity for tar reforming with toluene and naphthalene conversions of 0.8 in a short residence time of 0.17 s at 900 °C. A theoretical residence time to reach the complete naphthalene conversion was 1.2 s at 900 °C for palm shell char, demonstrating a promising activity similar to wood char and straw char, but better than CaO. It was also found that potassium and iron-loaded palm shell chars exhibited much better catalytic activity than palm shell char, while the parallel reaction of gasification of K-loaded palm shell char influenced the conversion with its drastic mass loss. Moreover, contrary to CaO, palm shell char presented relatively low selectivity to benzene, and its spontaneous gasification generated extra syngas. In summary, the present study demonstrated that the low-cost material, palm shell char, can successfully be used as the tar-reforming catalyst after SEG process.Item Open Access Measuring circularity in cities : a review of the scholarly and grey literature in search of evidence-based, measurable and actionable indicators(2023) Kapoor, Kartik; Amydala, Nikhil Sayi; Ambooken, Anubhav; Scheinberg, AnneCircularity in cities is key to Earth’s sustainable and resource-efficient future. In contrast to the broad framework of circular economy, circularity is a technical concept associated with avoiding disposal and prolonging the useful life of products and materials, and thereby extracting fewer resources. In search of metrics and indicators to measure the impacts of circular processes in cities in real time, the authors reviewed the literature on the circular economy and circularity, in search of evidence-based circularity indicators suitable for cities to use to benchmark the environmental and climate benefits of six waste prevention cascades. This paper reports on a systematic literature review using the PRISMA protocol to screen, evaluate, and review published and grey literature sources. From more than 15,000 papers screened, after application of criteria, fewer than 25 papers were found that presented evidence-based, measurable, and actionable indicators or indicator sets for benchmarking the performance of circular processes in cities. The authors concluded that the practical commitment to evidence-based tracking of circularity (in cities) is weak. Practical progress towards a circular economy and physical and economic circularity will require stakeholders to strengthen and test the very small number of indicators and indicator sets that are relevant and useful for cities and regions to use for measuring their progress towards becoming more circular, and increase evidence-based monitoring for circularity and the circular economy.Item Open Access Dynamic monitoring of Frequency Containment Reserve activation(2021) Maucher, Philipp; Lens, HendrikFrequency Containment Reserve (FCR), also known as primary control reserve, is the fastest active power reserve (APR) used for system balancing. In the past, FCR was provided by a limited number of large units and the technical requirements on FCR activation could be monitored by a manual procedure. Due to the fact that FCR increasingly is provided by a large number of smaller units, manual procedures are no viable option for the future. For this reason, this article describes an automated concept for monitoring the quality of the activation of FCR during operation. Before FCR monitoring can be carried out, however, the measured active power has to be apportioned among the scheduled power and the different APR products, as they may be provided simultaneously. This article presents a method for the separation of different APR products based on dynamic models. In the proposed monitoring concept, a tolerance channel is created based on the FCR setpoint, defining the admissible range for FCR activation. This tolerance channel is established by means of a dynamic model corresponding to the slowest reserve provider (RP) whose FCR activation is still considered to be compliant. For the purpose of evaluation for longer time periods, the actual FCR activation is normalized relative to the tolerance channel. Finally, the article discusses results obtained with the proposed monitoring concept for different kinds of non-compliant FCR activation such as limited or delayed activation.Item Open Access Parametric study on the adjustability of the syngas composition by sorption-enhanced gasification in a dual-fluidized bed pilot plant(2021) Hafner, Selina; Schmid, Max; Scheffknecht, GünterFinding a way for mitigating climate change is one of the main challenges of our generation. Sorption-enhanced gasification (SEG) is a process by which syngas as an important intermediate for the synthesis of e.g., dimethyl ether (DME), bio-synthetic natural gas (SNG) and Fischer-Tropsch (FT) products or hydrogen can be produced by using biomass as feedstock. It can, therefore, contribute to a replacement for fossil fuels to reduce greenhouse gas (GHG) emissions. SEG is an indirect gasification process that is operated in a dual-fluidized bed (DFB) reactor. By the use of a CO2-active sorbent as bed material, CO2 that is produced during gasification is directly captured. The resulting enhancement of the water-gas shift reaction enables the production of a syngas with high hydrogen content and adjustable H2/CO/CO2-ratio. Tests were conducted in a 200 kW DFB pilot-scale facility under industrially relevant conditions to analyze the influence of gasification temperature, steam to carbon (S/C) ratio and weight hourly space velocity (WHSV) on the syngas production, using wood pellets as feedstock and limestone as bed material. Results revealed a strong dependency of the syngas composition on the gasification temperature in terms of permanent gases, light hydrocarbons and tars. Also, S/C ratio and WHSV are parameters that can contribute to adjusting the syngas properties in such a way that it is optimized for a specific downstream synthesis process.Item Open Access Developing a cloud-based air quality monitoring platform using low-cost sensors(2024) Samad, Abdul; Kieser, Joschka; Chourdakis, Ioannis; Vogt, UlrichConventional air quality monitoring has been traditionally carried out in a few fixed places with expensive measuring equipment. This results in sparse spatial air quality data, which do not represent the real air quality of an entire area, e.g., when hot spots are missing. To obtain air quality data with higher spatial and temporal resolution, this research focused on developing a low-cost network of cloud-based air quality measurement platforms. These platforms should be able to measure air quality parameters including particulate matter (PM10, PM2.5, PM1) as well as gases like NO, NO2, O3, and CO, air temperature, and relative humidity. These parameters were measured every second and transmitted to a cloud server every minute on average. The platform developed during this research used one main computer to read the sensor data, process it, and store it in the cloud. Three prototypes were tested in the field: two of them at a busy traffic site in Stuttgart, Marienplatz and one at a remote site, Ötisheim, where measurements were performed near busy railroad tracks. The developed platform had around 1500 € in materials costs for one Air Quality Sensor Node and proved to be robust during the measurement phase. The notion of employing a Proportional-Integral-Derivative (PID) controller for the efficient working of a dryer that is used to reduce the negative effect of meteorological parameters such as air temperature and relative humidity on the measurement results was also pursued. This is seen as one way to improve the quality of data captured by low-cost sensors.Item Open Access Feasibility study on the use of NO2 and PM2.5 sensors for exposure assessment and indoor source apportionment at fixed locations(2024) Chacón-Mateos, Miriam; Remy, Erika; Liebers, Uta; Heimann, Frank; Witt, Christian; Vogt, UlrichRecent advances in sensor technology for air pollution monitoring open new possibilities in the field of environmental epidemiology. The low spatial resolution of fixed outdoor measurement stations and modelling uncertainties currently limit the understanding of personal exposure. In this context, air quality sensor systems (AQSSs) offer significant potential to enhance personal exposure assessment. A pilot study was conducted to investigate the feasibility of the NO2 sensor model B43F and the particulate matter (PM) sensor model OPC-R1, both from Alphasense (UK), for use in epidemiological studies. Seven patients with chronic obstructive pulmonary disease (COPD) or asthma had built-for-purpose sensor systems placed inside and outside of their homes at fixed locations for one month. Participants documented their indoor activities, presence in the house, window status, and symptom severity and performed a peak expiratory flow test. The potential inhaled doses of PM2.5 and NO2 were calculated using different data sources such as outdoor data from air quality monitoring stations, indoor data from AQSSs, and generic inhalation rates (IR) or activity-specific IR. Moreover, the relation between indoor and outdoor air quality obtained with AQSSs, an indoor source apportionment study, and an evaluation of the suitability of the AQSS data for studying the relationship between air quality and health were investigated. The results highlight the value of the sensor data and the importance of monitoring indoor air quality and activity patterns to avoid exposure misclassification. The use of AQSSs at fixed locations shows promise for larger-scale and/or long-term epidemiological studies.Item Open Access Nanoparticle emission and characterization from pre-dried lignite and bituminous coal co-combustion(2020) Avagianos, Ioannis; Vounatsos, Panagiotis; Papandreou, Ioannis; Maier, Jörg; Grammelis, Panagiotis; Kakaras, EmmanuelNowadays, the high share of electricity production from renewables drives coal-fired power plants to adopt a more flexible operation scheme and, at the same time, maintain flue gas emissions within respective standards. A 500 kWth pulverized coal furnace was used to study pre-dried lignite combustion or co-combustion as an available option for these plants. Bituminous coal from Czech Republic and pre-dried lignite from Greece were blended for the experiments. Particle emissions measurements with a heated Electrical Low Pressure Impactor (ELPI+) and Scanning Electron Microscopy with Energy Dispersive Spectroscopy (SEM/EDS) analyses were performed. The effect of the pre-dried lignite proportions in the fuel feed and the combustion conditions regarding the combustion air staging were the two parameters selected for this study. Skeletal density values were measured from the cyclone prior to the impactor. Results are depicted with respect to the aerodynamic and Stokes diameter for impactor stages. The presence of pre-dried lignite in the fuel blend lowers the particle matter (PM) PM2.5, PM1 and PM0.1 emissions, thus having a positive impact on ESP’s fractional and overall efficiency. The staged combustion air feed reduces the particle emissions in all cases. Sulfur content follows a pattern of higher concentration values for finer particles.Item Open Access Meteorological and air quality measurements in a city region with complex terrain : influence of meteorological phenomena on urban climate(2023) Samad, Abdul; Kiseleva, Olga; Holst, Christopher Claus; Wegener, Robert; Kossmann, Meinolf; Meusel, Gregor; Fiehn, Alina; Erbertseder, Thilo; Becker, Ralf; Roiger, Anke; Stanislawsky, Peter; Klemp, Dieter; Emeis, Stefan; Kalthoff, Norbert; Vogt, UlrichItem Open Access Evaluation of equivalent dynamic active distribution network models with individual and aggregated consideration of grid forming converters(2023) Ungerland, Jakob; Lens, HendrikDetailed active distribution network modeling in the context of stability studies of future power systems can be avoided by applying complexity‐reduced equivalent dynamic models. Previous work developed an approach to derive such equivalent dynamic network models of systems dominated by grid following and grid forming converters. Nevertheless, this approach lacks an investigation of the aggregation of multiple grid forming converters to one equivalent component. Also, the approach needs to be evaluated for a closed ring topology to substantiate its validity independent of the detailed network topology. This work applies and validates the developed approach on active distribution networks in the context of three scenarios. The detailed and equivalent network models are simulated for three events and the results are used to compare the models with respect to accuracy and complexity. The derived equivalent dynamic network models with an individual representation of grid forming converters reproduce the dynamic behavior of the corresponding detailed networks very well. The aggregation of grid forming converters results in an adequate reproduction of the detailed network's dynamic behavior under the constraint of aggregating only neighboring grid forming converters of one branch. This allows for the consideration of the detailed network's topology in the corresponding equivalent dynamic model.Item Open Access Oxy-combustion of solid recovered fuel in a semi-industrial CFB reactor: on the implications of gas atmosphere and combustion temperature(2022) Moreno, Joseba; Schmid, Max; Scharr, Steven; Scheffknecht, GünterOxy-fuel combustion of refuse waste is gaining considerable attention as a viable CO2 negative technology that can enable the continued use of stationary combustion plants during the transition to renewable energy sources. Compared to fossil fuels, waste-derived fuels tend to be highly heterogeneous and to contain a greater amount of alkaline metals and chlorine. Therefore, experimental studies are mandatory to thoroughly elucidate refuse materials’ combustion and pollutant formation behavior. This paper presents an experimental investigation on the air and oxy-fuel combustion of solid recovered fuel at a 200 kWth circulating fluidized bed facility. In the course of two experimental campaigns, the effects of combustion atmosphere and temperature on pollutant formation (i.e., NOx, SO2, and HCl) and reactor hydrodynamics were systematically studied. In contrast to air-firing conditions, the experimental results showed that oxy-fuel combustion enhanced the volume concentration of NOx by about 50% while simultaneously decreasing the fuel-specific NOx emissions (by about 33%). The volume concentrations of SO2 and HCl were significantly influenced by the absorption capacity of calcium-containing ash particles, yielding corresponding values close to 10 and 200 ppmv at 871-880 °C under oxy-fuel combustion conditions. In addition, the analysis of hydrodynamic data revealed that smooth temperature profiles are indispensable to mitigate bed sintering and agglomeration risks during oxy-fuel operation. The results included in this study provide a valuable contribution to the database of experimental information on the oxy-fuel combustion of alternative fuels, which can be applied in future process model validations and scale-up studies.
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