04 Fakultät Energie-, Verfahrens- und Biotechnik
Permanent URI for this collectionhttps://elib.uni-stuttgart.de/handle/11682/5
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Item Open Access Miscibility and phase separation in PMMA/SAN blends investigated by nanoscale AFM-IR(2021) Resch, Julia; Dreier, Julia; Bonten, Christian; Kreutzbruck, MarcItem Open Access Insights into the processing of recycled carbon fibers via injection molding compounding(2020) Wellekötter, Jochen; Resch, Julia; Baz, Stephan; Gresser, Götz Theo; Bonten, ChristianAlthough fiber-reinforced plastics combine high strength and stiffness with being lightweight, major difficulties arise with high volume production and the return of manufactured parts back into the cycle of materials at the end of their lifecycles. In a novel approach, structural parts were produced from recycled material while utilizing the so-called injection molding compounding process. Recycled fibers and recycled polyamide matrix material were used by blending carbon and matrix fibers into a sliver before processing. Injection molding was then used to produce long fiber-reinforced parts through a direct fiber feed system. Recycled matrix granules were incorporated into the injection molding process by means of an injection molding compounder to investigate their influences on the mechanical properties of the parts. The findings show that the recycled fibers and matrix perform well in standardized tests, although fiber length and fiber content vary significantly and remain below expectations.Item Open Access Microplastics persist in an arable soil but do not affect soil microbial biomass, enzyme activities, and crop yield(2022) Schöpfer, Lion; Möller, Julia N.; Steiner, Thomas; Schnepf, Uwe; Marhan, Sven; Resch, Julia; Bayha, Ansilla; Löder, Martin G. J.; Freitag, Ruth; Brümmer, Franz; Laforsch, Christian; Streck, Thilo; Forberger, Jens; Kranert, Martin; Kandeler, Ellen; Pagel, HolgerMicroplastics (MP, plastic particles <5 mm) are ubiquitous in arable soils due to significant inputs via organic fertilizers, sewage sludges, and plastic mulches. However, knowledge of typical MP loadings, their fate, and ecological impacts on arable soils is limited. We studied (1) MP background concentrations, (2) the fate of added conventional and biodegradable MP, and (3) effects of MP in combination with organic fertilizers on microbial abundance and activity associated with carbon (C) cycling, and crop yields in an arable soil. On a conventionally managed soil (Luvisol, silt loam), we arranged plots in a randomized complete block design with the following MP treatments (none, low‐density polyethylene [LDPE], a blend of poly(lactic acid) and poly(butylene adipate‐co‐terephthalate) [PLA/PBAT]) and organic fertilizers (none, compost, digestate). We added 20 kg MP ha-1 and 10 t organic fertilizers ha-1. We measured concentrations of MP in the soil, microbiological indicators of C cycling (microbial biomass and enzyme activities), and crop yields over 1.5 years. Background concentration of MP in the top 10 cm was 296 ± 110 (mean ± standard error) particles <0.5 mm per kg soil, with polypropylene, polystyrene, and polyethylene as the main polymers. Added LDPE and PLA/PBAT particles showed no changes in number and particle size over time. MP did not affect the soil microbiological indicators of C cycling or crop yields. Numerous MP occur in arable soils, suggesting diffuse MP entry into soils. In addition to conventional MP, biodegradable MP may persist under field conditions. However, MP at current concentrations are not expected to affect C turnover and crop yield.Item Open Access In situ laboratory for plastic degradation in the Red Sea(2022) Brümmer, Franz; Schnepf, Uwe; Resch, Julia; Jemmali, Raouf; Abdi, Rahma; Kamel, Hesham Mostafa; Bonten, Christian; Müller, Ralph-WalterDegradation and fragmentation of plastics in the environment are still poorly understood. This is partly caused by the lack of long-term studies and methods that determine weathering duration. We here present a novel study object that preserves information on plastic age: microplastic (MP) resin pellets from the wreck of the SS Hamada, a ship that foundered twenty-nine years ago at the coast of Wadi el Gemal national park, Egypt. Its sinking date enabled us to precisely determine how long MP rested in the wreck and a nearby beach, on which part of the load was washed off. Pellets from both sampling sites were analyzed by microscopy, X-ray tomography, spectroscopy, calorimetry, gel permeation chromatography, and rheology. Most pellets were made of low-density polyethylene, but a minor proportion also consisted of high-density polyethylene. MP from inside the wreck showed no signs of degradation compared to pristine reference samples. Contrary, beached plastics exhibited changes on all structural levels, which sometimes caused fragmentation. These findings provide further evidence that plastic degradation under saltwater conditions is comparatively slow, whereas UV radiation and high temperatures on beaches are major drivers of that process. Future long-term studies should focus on underlying mechanisms and timescales of plastic degradation.