08 Fakultät Mathematik und Physik
Permanent URI for this collectionhttps://elib.uni-stuttgart.de/handle/11682/9
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Item Open Access Numerical study of the thermodynamic uncertainty relation for the KPZ-equation(2021) Niggemann, Oliver; Seifert, UdoA general framework for the field-theoretic thermodynamic uncertainty relation was recently proposed and illustrated with the (1+1) dimensional Kardar-Parisi-Zhang equation. In the present paper, the analytical results obtained there in the weak coupling limit are tested via a direct numerical simulation of the KPZ equation with good agreement. The accuracy of the numerical results varies with the respective choice of discretization of the KPZ non-linearity. Whereas the numerical simulations strongly support the analytical predictions, an inherent limitation to the accuracy of the approximation to the total entropy production is found. In an analytical treatment of a generalized discretization of the KPZ non-linearity, the origin of this limitation is explained and shown to be an intrinsic property of the employed discretization scheme.Item Open Access The two scaling regimes of the thermodynamic uncertainty relation for the KPZ-equation(2021) Niggemann, Oliver; Seifert, UdoWe investigate the thermodynamic uncertainty relation for the (1+1) dimensional Kardar-Parisi-Zhang (KPZ) equation on a finite spatial interval. In particular, we extend the results for small coupling strengths obtained previously to large values of the coupling parameter. It will be shown that, due to the scaling behavior of the KPZ equation, the thermodynamic uncertainty relation (TUR) product displays two distinct regimes which are separated by a critical value of an effective coupling parameter. The asymptotic behavior below and above the critical threshold is explored analytically. For small coupling, we determine this product perturbatively including the fourth order; for strong coupling we employ a dynamical renormalization group approach. Whereas the TUR product approaches a value of 5 in the weak coupling limit, it asymptotically displays a linear increase with the coupling parameter for strong couplings. The analytical results are then compared to direct numerical simulations of the KPZ equation showing convincing agreement.Item Open Access Nonequilibrium sensing and its analogy to kinetic proofreading(2015) Hartich, David; Barato, Andre C.; Seifert, UdoFor a paradigmatic model of chemotaxis, we analyze the effect of how a nonzero affinity driving receptors out of equilibrium affects sensitivity. This affinity arises whenever changes in receptor activity involve adenosine triphosphate hydrolysis. The sensitivity integrated over a ligand concentration range is shown to be enhanced by the affinity, providing a measure of how much energy consumption improves sensing. With this integrated sensitivity we can establish an intriguing analogy between sensing with nonequilibrium receptors and kinetic proofreading: the increase in integrated sensitivity is equivalent to the decrease of the error in kinetic proofreading. The influence of the occupancy of the receptor on the phosphorylation and dephosphorylation reaction rates is shown to be crucial for the relation between integrated sensitivity and affinity. This influence can even lead to a regime where a nonzero affinity decreases the integrated sensitivity, which corresponds to anti-proofreading.Item Open Access Field-theoretic thermodynamic uncertainty relation : general formulation exemplified with the Kardar-Parisi-Zhang equation(2020) Niggemann, Oliver; Seifert, UdoWe propose a field-theoretic thermodynamic uncertainty relation as an extension of the one derived so far for a Markovian dynamics on a discrete set of states and for overdamped Langevin equations. We first formulate a framework which describes quantities like current, entropy production and diffusivity in the case of a generic field theory. We will then apply this general setting to the one-dimensional Kardar-Parisi-Zhang equation, a paradigmatic example of a non-linear field-theoretic Langevin equation. In particular, we will treat the dimensionless Kardar-Parisi-Zhang equation with an effective coupling parameter measuring the strength of the non-linearity. It will be shown that a field-theoretic thermodynamic uncertainty relation holds up to second order in a perturbation expansion with respect to a small effective coupling constant. The calculations show that the field-theoretic variant of the thermodynamic uncertainty relation is not saturated for the case of the Kardar-Parisi-Zhang equation due to an excess term stemming from its non-linearity.Item Open Access Thermodynamics of micro- and nano-systems driven by periodic temperature variations(2015) Brandner, Kay; Saito, Keiji; Seifert, UdoItem Open Access Functional integral approach to time-dependent heat exchange in open quantum systems : general method and applications(2015) Carrega, M.; Solinas, P.; Braggio, A.; Sassetti, M.; Weiß, UlrichWe establish the path integral approach for the time-dependent heat exchange of an externally driven quantum system coupled to a thermal reservoir. We derive the relevant influence functional and present an exact formal expression for the moment generating functional which carries all statistical properties of the heat exchange process for general linear dissipation. The method is applied to the time-dependent average heat transfer in the dissipative two-state system (TSS). We show that the heat can be written as a convolution integral which involves the population and coherence correlation functions of the TSS and additional correlations due to a polarization of the reservoir. The corresponding expression can be solved in the weak-damping limit both for white noise and for quantum mechanical coloured noise. The implications of pure quantum effects are discussed. Altogether a complete description of the dynamics of the average heat transfer ranging from the classical regime down to zero temperature is achieved.Item Open Access Coherence-enhanced efficiency of feedback-driven quantum engines(2015) Brandner, Kay; Bauer, Michael; Schmid, Michael T.; Seifert, UdoA genuine feature of projective quantum measurements is that they inevitably alter the mean energy of the observed system if the measured quantity does not commute with the Hamiltonian. Compared to the classical case, Jacobs proved that this additional energetic cost leads to a stronger bound on the work extractable after a single measurement from a system initially in thermal equilibrium (2009 Phys. Rev. A 80 012322). Here, we extend this bound to a large class of feedback-driven quantum engines operating periodically and in finite time. The bound thus implies a natural definition for the efficiency of information to work conversion in such devices. For a simple model consisting of a laser-driven two-level system, we maximize the efficiency with respect to the observable whose measurement is used to control the feedback operations. We find that the optimal observable typically does not commute with the Hamiltonian and hence would not be available in a classical two level system. This result reveals that periodic feedback engines operating in the quantum realm can exploit quantum coherences to enhance efficiency.Item Open Access Inferring kinetics and entropy production from observable transitions in partially accessible, periodically driven Markov networks(2024) Maier, Alexander M.; Degünther, Julius; Meer, Jann van der; Seifert, UdoFor a network of discrete states with a periodically driven Markovian dynamics, we develop an inference scheme for an external observer who has access to some transitions. Based on waiting-time distributions between these transitions, the periodic probabilities of states connected by these observed transitions and their time-dependent transition rates can be inferred. Moreover, the smallest number of hidden transitions between accessible ones and some of their transition rates can be extracted. We prove and conjecture lower bounds on the total entropy production for such periodic stationary states. Even though our techniques are based on generalizations of known methods for steady states, we obtain original results for those as well.Item Open Access Waiting time distributions in hybrid models of motor-bead assays: a concept and tool for inference(2023) Ertel, Benjamin; Meer, Jann van der; Seifert, UdoItem Open Access Thermodynamic inference in partially accessible Markov networks: a unifying perspective from transition-based waiting time distributions(2022) Meer, Jann van der; Ertel, Benjamin; Seifert, UdoThe inference of thermodynamic quantities from the description of an only partially accessible physical system is a central challenge in stochastic thermodynamics. A common approach is coarse-graining, which maps the dynamics of such a system to a reduced effective one. While coarse-graining states of the system into compound ones is a well-studied concept, recent evidence hints at a complementary description by considering observable transitions and waiting times. In this work, we consider waiting time distributions between two consecutive transitions of a partially observable Markov network. We formulate an entropy estimator using their ratios to quantify irreversibility. Depending on the complexity of the underlying network, we formulate criteria to infer whether the entropy estimator recovers the full physical entropy production or whether it just provides a lower bound that improves on established results. This conceptual approach, which is based on the irreversibility of underlying cycles, additionally enables us to derive estimators for the topology of the network, i.e., the presence of a hidden cycle, its number of states, and its driving affinity. Adopting an equivalent semi-Markov description, our results can be condensed into a fluctuation theorem for the corresponding semi-Markov process. This mathematical perspective provides a unifying framework for the entropy estimators considered here and established earlier ones. The crucial role of the correct version of time reversal helps to clarify a recent debate on the meaning of formal versus physical irreversibility. Extensive numerical calculations based on a direct evaluation of waiting time distributions illustrate our exact results and provide an estimate on the quality of the bounds for affinities of hidden cycles.