Universität Stuttgart
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Item Open Access Zukunft der Optik(1970) Tiziani, Hans J.Die Optik hat in den letzten Jahren neuen Aufschwung genommen. Mitverantwortlich für diese Entwicklung sind sowohl die Verwendung von leistungsfähigen Computern als auch die Nachfrage nach immer besserer Auflösung und Bildqualität. Besonders positiv haben sich die Entwicklungen des Laser (1960) und der Holographie ausgewirkt. Immer neue Applikationen des gebündelten, kohärenten Laserlichtes werden erschlossen, doch will ich mich in diesem Zusammenhang auf die mögliche Weiterentwlckung der erwähnten Gebiete beschränken.Item Open Access Dynamics of poling PVDF between 25°C and 120°C(1991) Eberle, Gernot; Eisenmenger, WolfgangPVDF films with high β-content are poled in an electric field of 60 MV/m at temperatures between 25°C and 120°C. At 25°C the alignment of dipoles takes place in a central poling zone during several hours of poling. When the temperature is increased to 120°C the poling time necessary to align the dipoles in this narrow zone is reduced to several seconds. In addition, at temperatures higher than 90°C and increased poling times the central poling zone first increases but later decreases in its dielectric displacement. Simultaneously in a 10 μm regime adjoining the positive electrode a secondary displacement zone starts to grow. The strong reduction of this peak under short circuit conditions indicates hetero-charge accumulation in front of an anode.Item Open Access Excited electronic states of flavin-containing coenzyme models(1988) Gückel, Friedemann; Schweitzer, Dieter; Becker, Katja; Schirmer, Rolf Heiner; Zipplies, Matthias F.; Staab, Heinz A.In order to gain further insight into the physical basis of flavin-catalyzed reactions, the interactions of a flavin with a second flavin and with other aromatic ring systems were studied. For this purpose compounds through 1 were synthesized These compounds contain the interacting units in defined geometric orientation. A monomeric flavin and glutathione reductase a flavoenzyme of known active-site chemistry, were included as reference molecules. The present report deals with excited triplet states of the flavin compounds as studied by optical spectroscopy and optically detected magnetic resonances (ODMR) at 1.3K.Item Open Access Fusionsforschung : eine Einführung(2020) Köhn-Seemann, AlfIn diesem Vortrag wird ein Überblick und eine Einleitung in das Gebiet der Fusionsforschung gegeben.Item Open Access Nuclear magnetic shielding tensors for 1H, 13C, and 15N in organic solids(1975) Spiess, Hans Wolfgang; Haeberlen, Ulrich; Kempf, Jürgen; Schweitzer, DieterA survey will be given of nuclear magnetic shielding tensors obtained by multiple pulse techniques for 1H in carboxylic acids and by high field NMR for 13C in carbonyl- and carboxyl groups of aromatic compounds and for 15N in pyridine and nitrobenzene.Item Open Access Self-consistent modelling of pulsar magnetospheres(1989) Herold, Heinz; Ertl, Thomas; Finkbeiner, Bernd; Ruder, HannsThe magnetosphere of a rapidly rotating, strongly magnetized neutron star with aligned magnetic and rotational axes (parallel rotator) is modelled numerically. Including the radiation of the particles accelerated to relativistic energies as an efficient damping mechanism, we obtain a quasi-stationary selfconsistent solution to this classical problem. The numerical simulation, which was started from the well-known vacuum solution, yields a global magnetospheric structure that can be characterized by two regions of oppositely charged particles, which eventually produce a relativistic pulsar wind, separated by a vacuum gap of considerable extent.Item Open Access Metallic coordination polymers using CS2 as starting material(1987) Keller, Heimo J.; Klutz, Thomas; Münstedt, Helmut; Renner, Gerd; Schweitzer, DieterOrganic polymers with "metallic" properties have found widespread interest during the last few years. Acetylene and aniline as well as different nitrogen and sulfur heterocycles have been used as starting materials. One main problem hampering the technical application of these solids up to now is their environmental and thermal instability. Therefore, we introduced metal ions to stabilize polymeric backbones with high electrical conductivity. Because of the enormous coordination ability of sulfur to many transition metal ions we decided to use a polymeric carbon-sulfur backbone.Item Open Access Phonon detection by the fountain pressure in superfluid 4Helium films(1980) Eisenmenger, WolfgangThe importance of phonon focussing was first demonstrated by Taylor, Maris and Elbaum, who calculated the phonon intensities or different modes in single crystals from the detailed form of the angle or k-dependent sound velocity surfaces. The results of these calculations are well-confirmed by experiment. It is quite surprising that phonon focussing leads in several crystals to very narrow beams of phonon energy propagation especially for transverse modes, as recently calculated by Rosch and Weis, who presented their computer results in a very instructive form. From these theoretical results it appears worthwhile to devise methods by which the intensity distribution of incoherent phonons propagating in single crystals can be measured in detail or directly imaged.Item Open Access Application of interferometry and holography for precision measurements(1984) Tiziani, Hans J.Phase measurement techniques are becoming a useful tool for precision measurements. Spatial as well as temporal phase shift methods can be used. Optical testing, where computer analysis of interference fringes is becoming increasing important, will be discussed in connection with testing optical components, microprofiles as well as for testing aspheric surfaces. In addition, methods using heterodyne techniques and real time holography will be described.Item Open Access Field induced gas emission of polymer films(1992) Selle, Michael; Eberle, Gernot; Gompf, Bruno; Eisenmenger, WolfgangPoling polyvinylidene fluoride under vacuum conditions causes strong gas emission, which is analyzed with a quadrupole mass spectrometer. The dominant peak in the mass spectrum is HF, which is produced by electrochemical reactions at the sample surface. After the electric field is switched off, the gas emission unexpectedly increases to a value higher than under the field. This can be explained by ionic charge detrappingand charge migration