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http://dx.doi.org/10.18419/opus-12233
Autor(en): | Krüger, Ekkehard |
Titel: | Magnetic bands producing a monoclinic magnetic structure in NiO, FeO, MnO, and a tetragonal one in CoO |
Erscheinungsdatum: | 2022 |
Dokumentart: | Zeitschriftenartikel |
Seiten: | 7 |
Erschienen in: | Symmetry 14 (2022), No. 1285 |
URI: | http://nbn-resolving.de/urn:nbn:de:bsz:93-opus-ds-122504 http://elib.uni-stuttgart.de/handle/11682/12250 http://dx.doi.org/10.18419/opus-12233 |
ISSN: | 2073-8994 |
Zusammenfassung: | In a foregoing paper, the author reported evidence that the multi-spin-axis magnetic structure proposed in 1964 by van Laar is realized in antiferromagnetic CoO. Within the nonadiabatic Heisenberg model, this tetragonal body-centered structure is generated by atomic-like electrons in a special magnetic band of CoO, a mechanism that may emerge only because the nonadiabatic Heisenberg model goes beyond the adiabatic approximation. This paper compares the band structures of the transition-metal monoxides NiO, CoO, FeO, and MnO, and shows that only CoO possesses a magnetic band which may produce the tetragonal magnetic structure proposed by van Laar. The magnetic bands of the other monoxides, NiO, FeO, and MnO, are clearly related to the monoclinic base-centered magnetic structure experimentally observed in these materials. |
Enthalten in den Sammlungen: | 03 Fakultät Chemie |
Dateien zu dieser Ressource:
Datei | Beschreibung | Größe | Format | |
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symmetry-14-01285-v2.pdf | 320,35 kB | Adobe PDF | Öffnen/Anzeigen |
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