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http://dx.doi.org/10.18419/opus-14449
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| DC Element | Wert | Sprache |
|---|---|---|
| dc.contributor.author | Hoslauer, Jean‐Louis | - |
| dc.contributor.author | Lissner, Falk | - |
| dc.contributor.author | Blaschkowski, Björn | - |
| dc.contributor.author | Schleid, Thomas | - |
| dc.date.accessioned | 2024-06-04T08:24:45Z | - |
| dc.date.available | 2024-06-04T08:24:45Z | - |
| dc.date.issued | 2020 | de |
| dc.identifier.issn | 1521-3749 | - |
| dc.identifier.issn | 0044-2313 | - |
| dc.identifier.other | 1891303279 | - |
| dc.identifier.uri | http://nbn-resolving.de/urn:nbn:de:bsz:93-opus-ds-144681 | de |
| dc.identifier.uri | http://elib.uni-stuttgart.de/handle/11682/14468 | - |
| dc.identifier.uri | http://dx.doi.org/10.18419/opus-14449 | - |
| dc.description.abstract | The europium(II) oxoborate Li2Eu3Br2[BO3]2 featuring lithium and bromide ions was synthesized by the reaction of Eu2O3 with Li[BH4] as lithium‐ and boron‐ as well as EuBr3 as bromide‐source at 750 °C for 24 h in silica‐jacketed sealed niobium capsules. The yellow, air‐stable and yellow fluorescent compound crystallizes in the trigonal space group R3m (a = 1049.06(7) pm, c = 2993.1(3) pm, c/a = 2.853, Z = 12). The two crystallographically distinguishable Eu2+ cations show either an eightfold coordination as bicapped trigonal prism ([EuO6Br2]12-) or a ninefold coordination as monocapped square antiprism ([EuO5Br4]12-). All oxygen atoms stem from isolated triangular [BO3]3- anions and the Li+ cations reside in octahedral voids provided by both oxygen atoms and Br- anions. | en |
| dc.description.sponsorship | Projekt DEAL | de |
| dc.language.iso | en | de |
| dc.relation.uri | doi:10.1002/zaac.202000227 | de |
| dc.rights | info:eu-repo/semantics/openAccess | de |
| dc.rights.uri | https://creativecommons.org/licenses/by-nc-nd/4.0/ | de |
| dc.subject.ddc | 540 | de |
| dc.title | Li2Eu3Br2[BO3]2 : a new europium(II) halide oxoborate with yellow luminescence | en |
| dc.type | article | de |
| dc.date.updated | 2023-11-14T05:52:02Z | - |
| ubs.fakultaet | Chemie | de |
| ubs.institut | Institut für Anorganische Chemie | de |
| ubs.publikation.seiten | 1774-1781 | de |
| ubs.publikation.source | Zeitschrift für anorganische und allgemeine Chemie 646 (2020), S. 1774-1781 | de |
| ubs.publikation.typ | Zeitschriftenartikel | de |
| Enthalten in den Sammlungen: | 03 Fakultät Chemie | |
Dateien zu dieser Ressource:
| Datei | Beschreibung | Größe | Format | |
|---|---|---|---|---|
| ZAAC_ZAAC202000227.pdf | 2,36 MB | Adobe PDF | Öffnen/Anzeigen |
Diese Ressource wurde unter folgender Copyright-Bestimmung veröffentlicht: Lizenz von Creative Commons
