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http://dx.doi.org/10.18419/opus-14639
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DC Element | Wert | Sprache |
---|---|---|
dc.contributor.author | Hauser, Philipp M. | - |
dc.contributor.author | Ende, Melita van der | - |
dc.contributor.author | Groos, Jonas | - |
dc.contributor.author | Frey, Wolfgang | - |
dc.contributor.author | Wang, Dongren | - |
dc.contributor.author | Buchmeiser, Michael R. | - |
dc.date.accessioned | 2024-07-12T08:51:24Z | - |
dc.date.available | 2024-07-12T08:51:24Z | - |
dc.date.issued | 2020 | de |
dc.identifier.issn | 1099-0682 | - |
dc.identifier.issn | 1434-1948 | - |
dc.identifier.other | 1895510783 | - |
dc.identifier.uri | http://nbn-resolving.de/urn:nbn:de:bsz:93-opus-ds-146587 | de |
dc.identifier.uri | http://elib.uni-stuttgart.de/handle/11682/14658 | - |
dc.identifier.uri | http://dx.doi.org/10.18419/opus-14639 | - |
dc.description.abstract | The first cationic and neutral tungsten alkylidyne N‐heterocyclic carbene (NHC) complexes bearing one triflate ligand were synthesized and tested for their reactivity in alkyne metathesis. Both types of tungsten alkylidyne complexes display a higher productivity in alkyne metathesis than the analogous neutral tungsten alkylidyne NHC trisalkoxide complexes. Reaction of W(≡CC6H4OMe)(1,3‐bis(1‐hydroxy‐1,1‐trifluoromethylethyl)‐imidazol‐2‐ylidene)Cl (W18) with AgB(ArF)4 (ArF = 3,5‐bis(trifluoromethyl)phenyl) resulted in the unexpected formation of, to the best of our knowledge, the first cationic ditungstatetrahedrane W2(1,3‐bis(1‐hydroxy‐1,1‐trifluoromethyl‐ethyl)‐imidazol‐2‐ylidene)2(MeCN)(µ‐((Ar)CC(Ar)))+ (B(ArF)4)- (W19, Ar = C6H4OMe), which suggests bimolecular decomposition as a possible decomposition pathway of cationic tungsten alkylidyne NHC complexes. Reaction of the cationic tungsten alkylidyne NHC complex W(≡CC6H4OMe)(1,3‐diisopropylimidazol‐2‐ylidene)(OC(CF3)2Me)2(NCtBu)+ (B(ArF)4)- (W7) with 1‐phenyl‐1‐propyne allowed for the isolation of a cationic tungstacyclobutadiene W(C3(Ph)(Me)(C6H4OMe))(1,3‐diisopropylimidazol‐2‐ylidene)(OC(CF3)2Me)2(NCtBu)+ (B(ArF)4)- (W20). Its formation strongly supports a cationic active species in the alkyne metathesis with tungsten alkylidyne NHC complexes. | en |
dc.description.sponsorship | Deutsche Forschungsgemeinschaft | de |
dc.description.sponsorship | Projekt DEAL | de |
dc.language.iso | en | de |
dc.relation.uri | doi:10.1002/ejic.202000503 | de |
dc.rights | info:eu-repo/semantics/openAccess | de |
dc.rights.uri | https://creativecommons.org/licenses/by/4.0/ | de |
dc.subject.ddc | 540 | de |
dc.title | Cationic tungsten alkylidyne N‐heterocyclic carbene complexes : synthesis and reactivity in alkyne metathesis | en |
dc.type | article | de |
dc.date.updated | 2023-11-14T05:54:21Z | - |
ubs.fakultaet | Chemie | de |
ubs.institut | Institut für Organische Chemie | de |
ubs.institut | Institut für Polymerchemie | de |
ubs.publikation.seiten | 3070-3082 | de |
ubs.publikation.source | European journal of inorganic chemistry 2020 (2020), S. 3070-3082 | de |
ubs.publikation.typ | Zeitschriftenartikel | de |
Enthalten in den Sammlungen: | 03 Fakultät Chemie |
Dateien zu dieser Ressource:
Datei | Beschreibung | Größe | Format | |
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EJIC_EJIC202000503.pdf | 2,27 MB | Adobe PDF | Öffnen/Anzeigen |
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