08 Fakultät Mathematik und Physik

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    Organic metals from chiral BEDT-TTF donors
    (1991) Chen, Ben-ming; Deilacher, Frank; Hoch, Matthias; Keller, Heimo J.; Wu, Pei-ji; Gärtner, Stephan; Kahlich, Siegfried; Schweitzer, Dieter
    We have shown that is is possible to obtain organic metals from chiral molecules. The X-ray results prove an oxidation number of + 1.5 for the radical cations in at least two cases. To our best knowledge. these are: the first examples of BEDT-TTF-related radical cation salts with this oxidation number. As expected, we obtained statistically disordered crystals, containing the two different enantiomers in a "racemic" mixture. The broad smeared-out phase transitions are probably due to this disorder, or may be caused by the three-dimensional interactions which have been observed, so far, only once in a BEDT-TTF radical salt. We will crystallize the metallic compounds using "optically pure" isomers, in the hope to be able to isolate chiral metals.
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    Proton relaxation in the superconducting organic solid (BEDT-TTF)2Cu(NCS)2: evidence for relaxation by localized paramagnetic centers
    (1990) Klutz, Thomas; Haeberlen, Ulrich; Schweitzer, Dieter
    The nonexponential character of the build-up of the nuclear magnetization usually increases on lowering the temperature. Superconducting fluctuations have been offered in a speculative way as an explanation for the nonexponential spin relaxation. We have observed the same relaxation behaviour in our investigation of the proton spin relaxation in (BEDT-TTF)2Cu(NCS)2 which is an organic conductor at room temperature and becomes a superconductor at Tc=10.4 K at ambient pressure. As we noticed during preliminary measurements that the degree of deviation from exponential relaxation depends on the sample under study we decided to do experiments under controlled conditions of sample preparation.
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    Phonon absorption-spectroscopy in the presence of strong elastic phonon scattering
    (1986) Mebert, Joachim; Koblinger, Otto; Döttinger, Siegfried; Eisenmenger, Wolfgang
    In this work we show that in the presence of a strong phonon scattering background absorption structures can only be well resolved by reducing sample thickness to the phonon mean free path. This mean free path can be determined by analyzing the pulse shape of 285 GHz phonons. By reducing sample thickness to the appropriate value of 0,3mm the 21,2 cm -1 crystalline field transition in CaF 2:Er 3+ could be evaluated with the very high resolution of 5 GHz. In experiments performed on a 1mm thick LaF 3 Er 3+ sample we observed an absoption line at 14,2 cm -1 not visible in FIR absorption measurements.
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    Electric-field profiles in corona- or electron-beam-charged and thermally treated Teflon PTFE, FEP, and PFA films
    (1992) Gerhard-Multhaupt, Reimund; Eberle, Gernot; Xia, Zhongfou; Yang, Guomao; Eisenmenger, Wolfgang
    Charge spreading in three different types of Teflon electrets was studied by means of piezoelectrically generated pressure steps, FEP and PFA samples corona-charged at room temperature usually exhibited only a surface charge layer. Uniform charge spreading throughout the bulk was found in FEP charged at or heated to high temperatures. Charge spreading was much less prominent in PFA because of a smaller retrapping efficiency. In PTFE (polytetrafluorethylene), charges from the surface and the rear electrode were injected into the bulk during charging at any temperature. Electron-beam-deposited charge layers broadened significantly upon heating.
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    Band structure calculation and tunneling measurements in (BEDT-TTF)2X (X=I3, IAuI)
    (1990) Weger, Meir; Nowack, Andreas; Schweitzer, Dieter; Kübler, Jürgen; Bentum, Jan M. van; Sommers, Charles S.
    At about the same time when little proposed room-temperature superconductivity in organic polymers, it was suggested that the high-Tc of the more conventional A-15's is associated with their one-dimensional electronic band structure. When TTF-TCNQ was discovered in 1973, it was suggested that the electron-phonon coupling in this 1-D organic molecular crystal is responsible for the metal-to-insulator (Peierls) transition at 52 K2, and reducing λ will cause a crossover to a superconducting state. Since then, the electronic structure, the conduction mechanism, and the superconducting mechanism were subject to controversy. Therefore, it is of some importance to establish whether the electronic band structure, and conduction mechanism, are similar to those in more conventional metals, and whether the superconductivity mechanism is the normal BCS phonon-mediated interaction.
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    Phonon scattering due to deep acceptors in semiconductors
    (1976) Combarieu, Andre de; Lassmann, Kurt
    We have measured the magnetothermal conductivity in GaAs(Mn) and Si(In) for temperatures between 1.4 K and 90 K at magnetic fields up to 8 T. In both cases the dopants are deep acceptors with binding energy much larger (110 meV and 165 meV respectively) than given by the effective mass theory (~ 35 meV). There is a double interest in such systems: First, an excited level 3 meV (4.2 meV) above the acceptor ground state has been concluded from ultrasonic measurements. Such an excited state might be connected with a Jahn-Teller effect of these deeper acceptors and should be seen by resonant phonon scattering in thermal conductivity. Second, an anomalous behavior of the magnetothermal conductivity has been found for shallowacceptors in Ge (but not in Si) making comparison with systems with different g-factors desirable. The g-factors of acceptors in GaAs are roughly three times, the g-factor of Si(In) about 0.6 times that of Si(B).
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    Polarization profiles of electron-beam polarized VDF-TrFE copolymer films
    (1990) Schilling, Doris; Glatz-Reichenbach, Joachim; Dransfeld, Klaus; Bihler, Eckardt; Eisenmenger, Wolfgang
    In order to understand more clearly the poling mechanism in ferroelectric polymers, the PPS-technique was applied to copolymer films of vinylidenefluoride with trifluoroethylene P(VDF-TrFE), poled by a focused monoenergetic electron beam. Charges were injected in a well-defined way into the polymer films and thus provided information on the influence of externally introduced electrical charges on the poling process in ferroelectric polymers. The electron beam poling of P(VDF-TrFE) films is shown to produce very high values of polarization up to 180 mC/m2, which exceeds those produced in β-PVDF by electron irradiation by a factor of three. The distribution of the polarization across the film thickness is rather asymmetric, especially for samples irradiated with 20- and 30-KeV electrons. This may be caused by the rising electrical conductivity in samples with increasing electron energy. The annealing of the copolymer films before the poling procedure leads to a systematic increase of the polarization, with T a having its steepest rise around Tc.