08 Fakultät Mathematik und Physik
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Item Open Access Dynamics of poling PVDF between 25°C and 120°C(1991) Eberle, Gernot; Eisenmenger, WolfgangPVDF films with high β-content are poled in an electric field of 60 MV/m at temperatures between 25°C and 120°C. At 25°C the alignment of dipoles takes place in a central poling zone during several hours of poling. When the temperature is increased to 120°C the poling time necessary to align the dipoles in this narrow zone is reduced to several seconds. In addition, at temperatures higher than 90°C and increased poling times the central poling zone first increases but later decreases in its dielectric displacement. Simultaneously in a 10 μm regime adjoining the positive electrode a secondary displacement zone starts to grow. The strong reduction of this peak under short circuit conditions indicates hetero-charge accumulation in front of an anode.Item Open Access Phonon detection by the fountain pressure in superfluid 4Helium films(1980) Eisenmenger, WolfgangThe importance of phonon focussing was first demonstrated by Taylor, Maris and Elbaum, who calculated the phonon intensities or different modes in single crystals from the detailed form of the angle or k-dependent sound velocity surfaces. The results of these calculations are well-confirmed by experiment. It is quite surprising that phonon focussing leads in several crystals to very narrow beams of phonon energy propagation especially for transverse modes, as recently calculated by Rosch and Weis, who presented their computer results in a very instructive form. From these theoretical results it appears worthwhile to devise methods by which the intensity distribution of incoherent phonons propagating in single crystals can be measured in detail or directly imaged.Item Open Access Field induced gas emission of polymer films(1992) Selle, Michael; Eberle, Gernot; Gompf, Bruno; Eisenmenger, WolfgangPoling polyvinylidene fluoride under vacuum conditions causes strong gas emission, which is analyzed with a quadrupole mass spectrometer. The dominant peak in the mass spectrum is HF, which is produced by electrochemical reactions at the sample surface. After the electric field is switched off, the gas emission unexpectedly increases to a value higher than under the field. This can be explained by ionic charge detrappingand charge migrationItem Open Access Organic metals from chiral BEDT-TTF donors(1991) Chen, Ben-ming; Deilacher, Frank; Hoch, Matthias; Keller, Heimo J.; Wu, Pei-ji; Gärtner, Stephan; Kahlich, Siegfried; Schweitzer, DieterWe have shown that is is possible to obtain organic metals from chiral molecules. The X-ray results prove an oxidation number of + 1.5 for the radical cations in at least two cases. To our best knowledge. these are: the first examples of BEDT-TTF-related radical cation salts with this oxidation number. As expected, we obtained statistically disordered crystals, containing the two different enantiomers in a "racemic" mixture. The broad smeared-out phase transitions are probably due to this disorder, or may be caused by the three-dimensional interactions which have been observed, so far, only once in a BEDT-TTF radical salt. We will crystallize the metallic compounds using "optically pure" isomers, in the hope to be able to isolate chiral metals.Item Open Access High frequency phonon transmission through amorphous films(1990) Mebert, Joachim; Maile, Bernd; Eisenmenger, WolfgangWe now report on phonon spectroscopy measurements in the frequency range from 300 GHz - 1 THz on thin amorphous films of several materials (i.e. e-beam evaporated SiO2., α-Si and α-Ge). Some films were prepared in a residual gas atmosphere as H20 and N2.Item Open Access Nonequilibrium phonons(1980) Eisenmenger, WolfgangNonequilibrium phonon experiments with superconducting film tunneling junctions have demonstrated that phonon spectra produced by nonequilibrium quasiparticle distributions are well in accord with the predictions of theory. This is also demonstrated by the successful application of superconducting tunneling junctions for phonon absorption spectroscopy and recently also for phonon emission spectroscopy.Item Open Access Neuartige PVDF-Dünnschichtwandler für Ultraschallmessungen im GHz-Bereich(1985) Ambrosy, Anton; Holdik, Karl; Eisenmenger, WolfgangWegen seines hohen Piezoeffekts wird auch das Pol:ymer Polyvinylidenfluorid (PVDP) als Ultraschallwandler benutzt. Bisher war es jedoch nicht möglich PVDP-Wandler im GHz-Bereich zu verwenden, da für hochfrequente Anwendungen dünnere und ebenere Folien. als sie kommerziell angeboten werden, notwendig sind. Mit der nun folgenden Methode wurden nun erstmals PVDF-Dünnschichtwandler, die noch bei 24 GHz funktionieren, aus der Lösung hergestellt.Item Open Access Polarization distribution in PVDF obtained by poling under constant current condition(1990) Neumann, Guido; Bihler, Eckardt; Eberle, Gernot; Eisenmenger, WolfgangSince the resistivity of PVDE films increases when the films are poled, the voltage across the samples must be increased during the poling process in order to keep the current constant. Under these conditions, the formation of a polarization zone in the center of the film depth is observed. The thickness of the polarization-free zone close to the film surfaces is found to decrease with larger current densities. The results are consistent with a model assuming charge trapping in deep traps associated with the orientation of polar crystallites.Item Open Access Satellite phonon absorption lines above the 875 GHz resonance of interstitial oxygen in silicon(1987) Dittrich, Ehrenfried; Scheitler, Wolfgang; Eisenmenger, WolfgangAcoustic phonon spectroscopy with superconducting tunneling junctions as phonon generator and detector revealed a large number of sharp absorption lines between 875 GHz (oxygen resonance) and 1.35 THz for silicon doped with interstitial oxygen (Si:0i). The strength of these lines scales with the square of the oxygen concentration ranging from 1017 to 1018 cm-3. Under mechanical stress the lines show a frequency shift almost identical to the main oxygen resonance at 875 GHz as well as to the also observable isotope resonance. These satellite absorption lines are therefore discussed as 0i–0i neighbour interaction. This is supported by the influence of annealing.Item Open Access Polarization distributions in isotropic, stretched or annealed PVDF films(1988) Bihler, Eckardt; Holdik, Karl; Eisenmenger, WolfgangThe spatial distribution of the polarization in polyvinylidene fluoride (PVDF) films was measured at room temperature with the PPS (piezoelectric pressure step) method. In order to investigate the time development under external fields, a thin insulation polyethylene terephthalate (PET) film covering an evaporated aluminium electrode was inserted between the sample and the measuring electrode. The observed development of inhomogeneous and internal polarization zones is attributed to charge injection and charge trapping at the polarization zone boundaries. The polarization zone develops at a position where the critical field strength for dipole orientation in the crystallites is exceeded by the approach of injected homocharges (or without injection by the depletion of internal homocharges and the excess of heterocharges). The critical field for α-crystallites corresponds to an electric field phase transition at 1.2 MV/cm. The development of central polarization zones in PVDF containing β-crystallites indicates injection of charges with both signs and almost equal mobility. The results indicate that the β-crystallites determine the charge injection rate or the mobility or both.